A route to drastic increase of CO2 uptake in Zr metal organic framework UiO-66

Cher Hon Sam Lau, Ravichandar Babarao, Matthew Roland Hill

Research output: Contribution to journalArticleResearchpeer-review

142 Citations (Scopus)

Abstract

CO2 uptake in zirconium MOF UiO-66 almost doubles with post-synthetic exchange of Zr by Ti. This was due to smaller pore size and higher adsorption enthalpy, with good complementarity between experiment and simulation. Furthermore, the full effect is obtained with 50 Ti loading, precluding the need to fully substitute frameworks for CO2 capture.
Original languageEnglish
Pages (from-to)3634 - 3636
Number of pages3
JournalChemical Communications
Volume49
Issue number35
DOIs
Publication statusPublished - 2013
Externally publishedYes

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