TY - JOUR
T1 - A reduced-order model of concentration polarization in reverse osmosis systems with feed spacers
AU - Johnston, Jacob
AU - Dischinger, Sarah M.
AU - Nassr, Mostafa
AU - Lee, Ji Yeon
AU - Bigdelou, Pedram
AU - Freeman, Benny D.
AU - Gleason, Kristofer L.
AU - Martinand, Denis
AU - Miller, Daniel J.
AU - Molins, Sergi
AU - Spycher, Nicolas
AU - Stringfellow, William T.
AU - Tilton, Nils
N1 - Funding Information:
This work was generously funded by a National Science Foundation Career Award ( 1752531 ), the Embassy of France Thomas Jefferson Fund , and the National Alliance for Water Innovation (NAWI), which is funded by the U.S. Department of Energy , Energy Efficiency and Renewable Energy Office, Advanced Manufacturing Office under Funding Opportunity Announcement De-FOA-0001905 . The authors thank Dr. Tzahi Cath (Colorado School of Mines), Dr. John Farnsworth (University of Colorado, Boulder), Dr. Yarom Polsky (Oak Ridge National Laboratory), Dr. Eric Hoek (University of California, Los Angeles), and Dr. Hariswaran Sitaraman (National Renewable Energy Laboratory) for helpful discussions.
Funding Information:
This work was generously funded by a National Science Foundation Career Award (1752531), the Embassy of France Thomas Jefferson Fund, and the National Alliance for Water Innovation (NAWI), which is funded by the U.S. Department of Energy, Energy Efficiency and Renewable Energy Office, Advanced Manufacturing Office under Funding Opportunity Announcement De-FOA-0001905. The authors thank Dr. Tzahi Cath (Colorado School of Mines), Dr. John Farnsworth (University of Colorado, Boulder), Dr. Yarom Polsky (Oak Ridge National Laboratory), Dr. Eric Hoek (University of California, Los Angeles), and Dr. Hariswaran Sitaraman (National Renewable Energy Laboratory) for helpful discussions.
Publisher Copyright:
© 2023 Elsevier B.V.
PY - 2023/6/5
Y1 - 2023/6/5
N2 - Feed spacers in reverse osmosis systems generate complex fluid flows that limit computational fluid dynamics (CFD) simulations to small length and time scales. That limits our ability to simulate mineral scaling and other membrane fouling phenomena, which occur over longer length and time scales. Thus motivated, we develop a reduced model that replaces the CFD simulation of the velocity field with an analytical model that mimics spacers. This focuses the remaining numerical effort on simulating the advection–diffusion equation governing solute transport. We motivate and validate the model with CFD simulations and bench-scale experiments of spacer filaments in three different arrangements, including cases of unsteady vortex shedding. We show that the model produces a roughly 10,000-fold speedup compared to CFD, and accurately reproduces CFD predictions of not only the average and maximum concentrations, but also the local concentration distribution along the membrane. We also demonstrate the model for simulating a feed channel with a length-to-height ratio of 200. The model provides a simple testbed for exploratory studies of multispecies transport, precipitation, and membrane fouling phenomena for which simulating spacers is often prohibitive.
AB - Feed spacers in reverse osmosis systems generate complex fluid flows that limit computational fluid dynamics (CFD) simulations to small length and time scales. That limits our ability to simulate mineral scaling and other membrane fouling phenomena, which occur over longer length and time scales. Thus motivated, we develop a reduced model that replaces the CFD simulation of the velocity field with an analytical model that mimics spacers. This focuses the remaining numerical effort on simulating the advection–diffusion equation governing solute transport. We motivate and validate the model with CFD simulations and bench-scale experiments of spacer filaments in three different arrangements, including cases of unsteady vortex shedding. We show that the model produces a roughly 10,000-fold speedup compared to CFD, and accurately reproduces CFD predictions of not only the average and maximum concentrations, but also the local concentration distribution along the membrane. We also demonstrate the model for simulating a feed channel with a length-to-height ratio of 200. The model provides a simple testbed for exploratory studies of multispecies transport, precipitation, and membrane fouling phenomena for which simulating spacers is often prohibitive.
KW - Computational fluid dynamics
KW - Concentration polarization
KW - Feed spacers
KW - Reduced model
KW - Reverse osmosis
UR - https://www.scopus.com/pages/publications/85149797123
U2 - 10.1016/j.memsci.2023.121508
DO - 10.1016/j.memsci.2023.121508
M3 - Article
AN - SCOPUS:85149797123
SN - 0376-7388
VL - 675
JO - Journal of Membrane Science
JF - Journal of Membrane Science
M1 - 121508
ER -