A pyrazolate-stabilized sodium hydride complex

Andreas Stasch

doi:10.1039/c5cc00996k

A pyrazolate-stabilized sodium hydride complex

Andreas Stasch

School of Chemistry

Research output: Contribution to journal › Article › Research › peer-review

11 Citations (Scopus)

Abstract

The reaction of a sterically demanding sodium pyrazolate complex with n-butylsodium and diphenylsilane afforded the first well-defined molecular sodium hydride complex [(pz)6Na7H] 1 (pz = 3,5-di-tert-butylpyrazolate) that could be structurally characterised

Original language	English
Pages (from-to)	5056-5058
Number of pages	3
Journal	Chemical Communications
Volume	51
Issue number	24
DOIs	https://doi.org/10.1039/c5cc00996k
Publication status	Published - 2015

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10.1039/c5cc00996k

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title = "A pyrazolate-stabilized sodium hydride complex",

abstract = "The reaction of a sterically demanding sodium pyrazolate complex with n-butylsodium and diphenylsilane afforded the first well-defined molecular sodium hydride complex [(pz)6Na7H] 1 (pz = 3,5-di-tert-butylpyrazolate) that could be structurally characterised",

author = "Andreas Stasch",

year = "2015",

doi = "10.1039/c5cc00996k",

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AB - The reaction of a sterically demanding sodium pyrazolate complex with n-butylsodium and diphenylsilane afforded the first well-defined molecular sodium hydride complex [(pz)6Na7H] 1 (pz = 3,5-di-tert-butylpyrazolate) that could be structurally characterised

UR - http://pubs.rsc.org.ezproxy.lib.monash.edu.au/en/content/articlepdf/2015/cc/c5cc00996k

U2 - 10.1039/c5cc00996k

DO - 10.1039/c5cc00996k

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SP - 5056

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JO - Chemical Communications

JF - Chemical Communications

SN - 1359-7345

IS - 24

ER -

A pyrazolate-stabilized sodium hydride complex

Abstract

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Novel hydride complexes for chemical applications

New reactivity from unusual main group compounds

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A pyrazolate-stabilized sodium hydride complex

Abstract

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Projects

Novel hydride complexes for chemical applications

New reactivity from unusual main group compounds

Cite this