A polyoxometalate-based coordination polymer with the diamondoid topology

Susanna Mandic; Merinda R. Healey; Jan M. Gotthardt; Kerwyn G. Alley; Robert W. Gable; Chris Ritchie; Colette Boskovic

doi:10.1002/ejic.201200999

A polyoxometalate-based coordination polymer with the diamondoid topology

Susanna Mandic
, Merinda R. Healey
, Jan M. Gotthardt
, Kerwyn G. Alley
, Robert W. Gable
, Chris Ritchie
, Colette Boskovic

Research output: Contribution to journal › Article › Research › peer-review

23 Citations (Scopus)

Abstract

The new coordination polymer [ε-PMo₁₂O₃₇(OH) ₃{La(H₂O)₃}₄(L)]·28H ₂O [H₄L = tetrakis(4-carboxyphenyl)silane] can be synthesized by combining equal quantities of two types of 4-connecting building blocks: organic L^4- ligands and inorganic polyoxometalate-derived [ε-PMo₁₂O₃₇(OH)₃{La(H₂O) ₄}₄]⁴⁺ polyoxocations. The resulting coordination polymer exhibits the diamondoid topology, where both building blocks act as pseudotetrahedral nodes. The structural and spectroscopic characteristics of the parent polyoxocation are retained in the coordination polymer.

Original language	English
Pages (from-to)	1631-1634
Number of pages	4
Journal	European Journal of Inorganic Chemistry
Volume	2013
Issue number	10-11
DOIs	https://doi.org/10.1002/ejic.201200999
Publication status	Published - 1 Apr 2013
Externally published	Yes

Keywords

Coordination polymers
Lanthanoids
Metal-organic frameworks
Polyoxometalates

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10.1002/ejic.201200999

Cite this

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title = "A polyoxometalate-based coordination polymer with the diamondoid topology",

abstract = "The new coordination polymer [ε-PMo12O37(OH) 3\{La(H2O)3\}4(L)]·28H 2O [H4L = tetrakis(4-carboxyphenyl)silane] can be synthesized by combining equal quantities of two types of 4-connecting building blocks: organic L4- ligands and inorganic polyoxometalate-derived [ε-PMo12O37(OH)3\{La(H2O) 4\}4]4+ polyoxocations. The resulting coordination polymer exhibits the diamondoid topology, where both building blocks act as pseudotetrahedral nodes. The structural and spectroscopic characteristics of the parent polyoxocation are retained in the coordination polymer.",

keywords = "Coordination polymers, Lanthanoids, Metal-organic frameworks, Polyoxometalates",

author = "Susanna Mandic and Healey, \{Merinda R.\} and Gotthardt, \{Jan M.\} and Alley, \{Kerwyn G.\} and Gable, \{Robert W.\} and Chris Ritchie and Colette Boskovic",

year = "2013",

month = apr,

day = "1",

doi = "10.1002/ejic.201200999",

language = "English",

volume = "2013",

pages = "1631--1634",

journal = "European Journal of Inorganic Chemistry",

issn = "1434-1948",

publisher = "Wiley-VCH Verlag GmbH \& Co. KGaA",

number = "10-11",

}

TY - JOUR

T1 - A polyoxometalate-based coordination polymer with the diamondoid topology

AU - Mandic, Susanna

AU - Healey, Merinda R.

AU - Gotthardt, Jan M.

AU - Alley, Kerwyn G.

AU - Gable, Robert W.

AU - Ritchie, Chris

AU - Boskovic, Colette

PY - 2013/4/1

Y1 - 2013/4/1

N2 - The new coordination polymer [ε-PMo12O37(OH) 3{La(H2O)3}4(L)]·28H 2O [H4L = tetrakis(4-carboxyphenyl)silane] can be synthesized by combining equal quantities of two types of 4-connecting building blocks: organic L4- ligands and inorganic polyoxometalate-derived [ε-PMo12O37(OH)3{La(H2O) 4}4]4+ polyoxocations. The resulting coordination polymer exhibits the diamondoid topology, where both building blocks act as pseudotetrahedral nodes. The structural and spectroscopic characteristics of the parent polyoxocation are retained in the coordination polymer.

AB - The new coordination polymer [ε-PMo12O37(OH) 3{La(H2O)3}4(L)]·28H 2O [H4L = tetrakis(4-carboxyphenyl)silane] can be synthesized by combining equal quantities of two types of 4-connecting building blocks: organic L4- ligands and inorganic polyoxometalate-derived [ε-PMo12O37(OH)3{La(H2O) 4}4]4+ polyoxocations. The resulting coordination polymer exhibits the diamondoid topology, where both building blocks act as pseudotetrahedral nodes. The structural and spectroscopic characteristics of the parent polyoxocation are retained in the coordination polymer.

KW - Coordination polymers

KW - Lanthanoids

KW - Metal-organic frameworks

KW - Polyoxometalates

UR - https://www.scopus.com/pages/publications/84875671307

U2 - 10.1002/ejic.201200999

DO - 10.1002/ejic.201200999

M3 - Article

AN - SCOPUS:84875671307

SN - 1434-1948

VL - 2013

SP - 1631

EP - 1634

JO - European Journal of Inorganic Chemistry

JF - European Journal of Inorganic Chemistry

IS - 10-11

ER -

A polyoxometalate-based coordination polymer with the diamondoid topology

Abstract

Keywords

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