A one-pot synthesis to [(Me3Si)3SiSb]4; a potential precursor for Sb42-

Felipe García; Alexander D. Hopkins; Richard A. Kowenicki; Mary McPartlin; Yolanda Tesa

doi:10.1039/b405032k

A one-pot synthesis to [(Me₃Si)₃SiSb]₄; a potential precursor for Sb₄^2-

Felipe García
, Alexander D. Hopkins
, Richard A. Kowenicki
, Mary McPartlin
, Yolanda Tesa

Research output: Contribution to journal › Article › Research › peer-review

9 Citations (Scopus)

Abstract

The reaction of (Me₃Si)₃SiK · 18-crown-6 with SbCl₃ (3:1 equiv.) provides a simple route to the title complex [(Me₃Si)₃SiSb]₄. The potassium base initially acts as a nucleophile and then as a coupling agent, forming Sb-Sb bonds.

Original language	English
Pages (from-to)	2051-2052
Number of pages	2
Journal	Dalton Transactions
Issue number	14
DOIs	https://doi.org/10.1039/b405032k
Publication status	Published - 21 Jul 2004
Externally published	Yes

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10.1039/b405032k

Cite this

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title = "A one-pot synthesis to [(Me3Si)3SiSb]4; a potential precursor for Sb42-",

abstract = "The reaction of (Me3Si)3SiK · 18-crown-6 with SbCl3 (3:1 equiv.) provides a simple route to the title complex [(Me3Si)3SiSb]4. The potassium base initially acts as a nucleophile and then as a coupling agent, forming Sb-Sb bonds.",

author = "Felipe Garc{\'i}a and Hopkins, \{Alexander D.\} and Kowenicki, \{Richard A.\} and Mary McPartlin and Yolanda Tesa",

year = "2004",

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doi = "10.1039/b405032k",

language = "English",

pages = "2051--2052",

journal = "Dalton Transactions",

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publisher = "The Royal Society of Chemistry",

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T1 - A one-pot synthesis to [(Me3Si)3SiSb]4; a potential precursor for Sb42-

AU - García, Felipe

AU - Hopkins, Alexander D.

AU - Kowenicki, Richard A.

AU - McPartlin, Mary

AU - Tesa, Yolanda

PY - 2004/7/21

Y1 - 2004/7/21

N2 - The reaction of (Me3Si)3SiK · 18-crown-6 with SbCl3 (3:1 equiv.) provides a simple route to the title complex [(Me3Si)3SiSb]4. The potassium base initially acts as a nucleophile and then as a coupling agent, forming Sb-Sb bonds.

AB - The reaction of (Me3Si)3SiK · 18-crown-6 with SbCl3 (3:1 equiv.) provides a simple route to the title complex [(Me3Si)3SiSb]4. The potassium base initially acts as a nucleophile and then as a coupling agent, forming Sb-Sb bonds.

UR - https://www.scopus.com/pages/publications/3342933391

U2 - 10.1039/b405032k

DO - 10.1039/b405032k

M3 - Article

AN - SCOPUS:3342933391

SN - 1477-9226

SP - 2051

EP - 2052

JO - Dalton Transactions

JF - Dalton Transactions

IS - 14

ER -

A one-pot synthesis to [(Me3Si)3SiSb]4; a potential precursor for Sb42-

Abstract

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A one-pot synthesis to [(Me₃Si)₃SiSb]₄; a potential precursor for Sb₄^2-