A novel synthetic route to chalcogen substituted diphospholes

Matthew D. Francis; Cameron Jones; Christopher P. Morley

doi:10.1016/S0040-4039(99)00535-3

A novel synthetic route to chalcogen substituted diphospholes

Matthew D. Francis, Cameron Jones, Christopher P. Morley

Research output: Contribution to journal › Article › Research › peer-review

12 Citations (Scopus)

Abstract

The reaction of [Li(TMEDA)₂][1,2,4-SbP₂C₂Bu(t)₂] 1 with E(S₂CNEt₂)₂ (E = Se or Te) leads to the chalcogen substituted diphospholes [1,2,4-EP₂C₂Bu(t)₂] (E = Se 2, E = Te 3). Compound 3 represents the first example of a tellurium substituted diphosphole.

Original language	English
Pages (from-to)	3815-3816
Number of pages	2
Journal	Tetrahedron Letters
Volume	40
Issue number	19
DOIs	https://doi.org/10.1016/S0040-4039(99)00535-3
Publication status	Published - 7 May 1999
Externally published	Yes

Keywords

Low coordinate
Phosphorus
Selena- and telluradiphospholes
Selenium and tellurium NMR spectroscopy

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10.1016/S0040-4039(99)00535-3

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title = "A novel synthetic route to chalcogen substituted diphospholes",

abstract = "The reaction of [Li(TMEDA)2][1,2,4-SbP2C2Bu(t)2] 1 with E(S2CNEt2)2 (E = Se or Te) leads to the chalcogen substituted diphospholes [1,2,4-EP2C2Bu(t)2] (E = Se 2, E = Te 3). Compound 3 represents the first example of a tellurium substituted diphosphole.",

keywords = "Low coordinate, Phosphorus, Selena- and telluradiphospholes, Selenium and tellurium NMR spectroscopy",

author = "Francis, {Matthew D.} and Cameron Jones and Morley, {Christopher P.}",

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T1 - A novel synthetic route to chalcogen substituted diphospholes

AU - Francis, Matthew D.

AU - Jones, Cameron

AU - Morley, Christopher P.

PY - 1999/5/7

Y1 - 1999/5/7

N2 - The reaction of [Li(TMEDA)2][1,2,4-SbP2C2Bu(t)2] 1 with E(S2CNEt2)2 (E = Se or Te) leads to the chalcogen substituted diphospholes [1,2,4-EP2C2Bu(t)2] (E = Se 2, E = Te 3). Compound 3 represents the first example of a tellurium substituted diphosphole.

AB - The reaction of [Li(TMEDA)2][1,2,4-SbP2C2Bu(t)2] 1 with E(S2CNEt2)2 (E = Se or Te) leads to the chalcogen substituted diphospholes [1,2,4-EP2C2Bu(t)2] (E = Se 2, E = Te 3). Compound 3 represents the first example of a tellurium substituted diphosphole.

KW - Low coordinate

KW - Phosphorus

KW - Selena- and telluradiphospholes

KW - Selenium and tellurium NMR spectroscopy

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U2 - 10.1016/S0040-4039(99)00535-3

DO - 10.1016/S0040-4039(99)00535-3

M3 - Article

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SN - 0040-4039

VL - 40

SP - 3815

EP - 3816

JO - Tetrahedron Letters

JF - Tetrahedron Letters

IS - 19

ER -

A novel synthetic route to chalcogen substituted diphospholes

Abstract

Keywords

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