A novel organic peroxyester as an exclusive source of tert-butyl radicals

Tomoyuki Nakamura; Yasumasa Watanabe; Hiroshi Tezuka; W. Ken Busfield; Ian D. Jenkins; Ezio Rizzardo; San H. Thang; Shuji Suyama

doi:10.1246/cl.1997.1093

A novel organic peroxyester as an exclusive source of tert-butyl radicals

Tomoyuki Nakamura, Yasumasa Watanabe, Hiroshi Tezuka, W. Ken Busfield, Ian D. Jenkins, Ezio Rizzardo, San H. Thang, Shuji Suyama

Research output: Contribution to journal › Article › Research › peer-review

14 Citations (Scopus)

Abstract

A novel peroxyester, 1,1,2,2-tetramethylpropyl peroxypivalate 1b, has been synthesized and thermolyzed in cumene. The kinetic data show that the decomposition rate constant of 1b is about three times higher than that of tert-butyl peroxypivalate. The radical trapping technique employing 1,1,3,3-tetramethyl-2,3-dihydro-1H-isoindol-2-yloxyl has been used to study the decomposition mechanism of 1b. The results show that the thermolysis of 1b in cumene generates tert-butyl radicals exclusively.

Original language	English
Pages (from-to)	1093-1094
Number of pages	2
Journal	Chemistry Letters
Issue number	11
DOIs	https://doi.org/10.1246/cl.1997.1093
Publication status	Published - 1 Jan 1997

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10.1246/cl.1997.1093

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title = "A novel organic peroxyester as an exclusive source of tert-butyl radicals",

abstract = "A novel peroxyester, 1,1,2,2-tetramethylpropyl peroxypivalate 1b, has been synthesized and thermolyzed in cumene. The kinetic data show that the decomposition rate constant of 1b is about three times higher than that of tert-butyl peroxypivalate. The radical trapping technique employing 1,1,3,3-tetramethyl-2,3-dihydro-1H-isoindol-2-yloxyl has been used to study the decomposition mechanism of 1b. The results show that the thermolysis of 1b in cumene generates tert-butyl radicals exclusively.",

author = "Tomoyuki Nakamura and Yasumasa Watanabe and Hiroshi Tezuka and Busfield, \{W. Ken\} and Jenkins, \{Ian D.\} and Ezio Rizzardo and Thang, \{San H.\} and Shuji Suyama",

year = "1997",

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doi = "10.1246/cl.1997.1093",

language = "English",

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journal = "Chemistry Letters",

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T1 - A novel organic peroxyester as an exclusive source of tert-butyl radicals

AU - Nakamura, Tomoyuki

AU - Watanabe, Yasumasa

AU - Tezuka, Hiroshi

AU - Busfield, W. Ken

AU - Jenkins, Ian D.

AU - Rizzardo, Ezio

AU - Thang, San H.

AU - Suyama, Shuji

PY - 1997/1/1

Y1 - 1997/1/1

N2 - A novel peroxyester, 1,1,2,2-tetramethylpropyl peroxypivalate 1b, has been synthesized and thermolyzed in cumene. The kinetic data show that the decomposition rate constant of 1b is about three times higher than that of tert-butyl peroxypivalate. The radical trapping technique employing 1,1,3,3-tetramethyl-2,3-dihydro-1H-isoindol-2-yloxyl has been used to study the decomposition mechanism of 1b. The results show that the thermolysis of 1b in cumene generates tert-butyl radicals exclusively.

AB - A novel peroxyester, 1,1,2,2-tetramethylpropyl peroxypivalate 1b, has been synthesized and thermolyzed in cumene. The kinetic data show that the decomposition rate constant of 1b is about three times higher than that of tert-butyl peroxypivalate. The radical trapping technique employing 1,1,3,3-tetramethyl-2,3-dihydro-1H-isoindol-2-yloxyl has been used to study the decomposition mechanism of 1b. The results show that the thermolysis of 1b in cumene generates tert-butyl radicals exclusively.

UR - https://www.scopus.com/pages/publications/0031312245

U2 - 10.1246/cl.1997.1093

DO - 10.1246/cl.1997.1093

M3 - Article

AN - SCOPUS:0031312245

SN - 0366-7022

SP - 1093

EP - 1094

JO - Chemistry Letters

JF - Chemistry Letters

IS - 11

ER -

A novel organic peroxyester as an exclusive source of tert-butyl radicals

Abstract

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