A novel fabrication approach for multifunctional graphene-based thin film nano-composite membranes with enhanced desalination and antibacterial characteristics

Hanaa M. Hegab, Ahmed ElMekawy, Thomas G. Barclay, Andrew Michelmore, Linda Zou, Dusan Losic, Christopher P. Saint, Milena Ginic-Markovic

Research output: Contribution to journalArticleResearchpeer-review

10 Citations (Scopus)

Abstract

A practical fabrication technique is presented to tackle the trade-off between the water flux and salt rejection of thin film composite (TFC) reverse osmosis (RO) membranes through controlled creation of a thinner active selective polyamide (PA) layer. The new thin film nano-composite (TFNC) RO membranes were synthesized with multifunctional poly tannic acid-functionalized graphene oxide nanosheets (pTA-f-GO) embedded in its PA thin active layer, which is produced through interfacial polymerization. The incorporation of pTA-f-GOL into the fabricated TFNC membranes resulted in a thinner PA layer with lower roughness and higher hydrophilicity compared to pristine membrane. These properties enhanced both the membrane water flux (improved by 40%) and salt rejection (increased by 8%) of the TFNC membrane. Furthermore, the incorporation of biocidal pTA-f-GO nanosheets into the PA active layer contributed to improving the antibacterial properties by 80%, compared to pristine membrane. The fabrication of the pTA-f-GO nanosheets embedded in the PA layer presented in this study is a very practical, scalable and generic process that can potentially be applied in different types of separation membranes resulting in less energy consumption, increased cost-efficiency and improved performance.

Original languageEnglish
Article number7490
Number of pages10
JournalScientific Reports
Volume7
DOIs
Publication statusPublished - 8 Aug 2017
Externally publishedYes

Cite this

Hegab, Hanaa M. ; ElMekawy, Ahmed ; Barclay, Thomas G. ; Michelmore, Andrew ; Zou, Linda ; Losic, Dusan ; Saint, Christopher P. ; Ginic-Markovic, Milena. / A novel fabrication approach for multifunctional graphene-based thin film nano-composite membranes with enhanced desalination and antibacterial characteristics. In: Scientific Reports. 2017 ; Vol. 7.
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abstract = "A practical fabrication technique is presented to tackle the trade-off between the water flux and salt rejection of thin film composite (TFC) reverse osmosis (RO) membranes through controlled creation of a thinner active selective polyamide (PA) layer. The new thin film nano-composite (TFNC) RO membranes were synthesized with multifunctional poly tannic acid-functionalized graphene oxide nanosheets (pTA-f-GO) embedded in its PA thin active layer, which is produced through interfacial polymerization. The incorporation of pTA-f-GOL into the fabricated TFNC membranes resulted in a thinner PA layer with lower roughness and higher hydrophilicity compared to pristine membrane. These properties enhanced both the membrane water flux (improved by 40{\%}) and salt rejection (increased by 8{\%}) of the TFNC membrane. Furthermore, the incorporation of biocidal pTA-f-GO nanosheets into the PA active layer contributed to improving the antibacterial properties by 80{\%}, compared to pristine membrane. The fabrication of the pTA-f-GO nanosheets embedded in the PA layer presented in this study is a very practical, scalable and generic process that can potentially be applied in different types of separation membranes resulting in less energy consumption, increased cost-efficiency and improved performance.",
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A novel fabrication approach for multifunctional graphene-based thin film nano-composite membranes with enhanced desalination and antibacterial characteristics. / Hegab, Hanaa M.; ElMekawy, Ahmed; Barclay, Thomas G.; Michelmore, Andrew; Zou, Linda; Losic, Dusan; Saint, Christopher P.; Ginic-Markovic, Milena.

In: Scientific Reports, Vol. 7, 7490, 08.08.2017.

Research output: Contribution to journalArticleResearchpeer-review

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