A novel convergent approach to trans-fused polyether frameworks based on the reaction of vinylstannanes and triflates and its application to a synthetic study of the EFGH ring system of gambierol

Chie Kadowaki; Philip W.H. Chan; Isao Kadota; Yoshinori Yamamoto

doi:10.1016/S0040-4039(00)00952-7

A novel convergent approach to trans-fused polyether frameworks based on the reaction of vinylstannanes and triflates and its application to a synthetic study of the EFGH ring system of gambierol

Chie Kadowaki
, Philip W.H. Chan
, Isao Kadota
, Yoshinori Yamamoto

Research output: Contribution to journal › Article › Research › peer-review

36 Citations (Scopus)

Abstract

A new strategy for the convergent assembly of six-membered polycyclic ether ring fragments has been developed based upon the novel reaction between vinylstannanes with triflates in the presence of a strong base. The application of the present method has allowed for a synthetic study of the EFGH ring of gambierol to be achieved. (C) 2000 Elsevier Science Ltd.

Original language	English
Pages (from-to)	5769-5772
Number of pages	4
Journal	Tetrahedron Letters
Volume	41
Issue number	30
DOIs	https://doi.org/10.1016/S0040-4039(00)00952-7
Publication status	Published - 22 Jul 2000
Externally published	Yes

Keywords

Coupling
Polycyclic ether
Triflate
Vinylstannane

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10.1016/S0040-4039(00)00952-7

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title = "A novel convergent approach to trans-fused polyether frameworks based on the reaction of vinylstannanes and triflates and its application to a synthetic study of the EFGH ring system of gambierol",

abstract = "A new strategy for the convergent assembly of six-membered polycyclic ether ring fragments has been developed based upon the novel reaction between vinylstannanes with triflates in the presence of a strong base. The application of the present method has allowed for a synthetic study of the EFGH ring of gambierol to be achieved. (C) 2000 Elsevier Science Ltd.",

keywords = "Coupling, Polycyclic ether, Triflate, Vinylstannane",

author = "Chie Kadowaki and Chan, \{Philip W.H.\} and Isao Kadota and Yoshinori Yamamoto",

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doi = "10.1016/S0040-4039(00)00952-7",

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A novel convergent approach to trans-fused polyether frameworks based on the reaction of vinylstannanes and triflates and its application to a synthetic study of the EFGH ring system of gambierol. / Kadowaki, Chie; Chan, Philip W.H.; Kadota, Isao et al.
In: Tetrahedron Letters, Vol. 41, No. 30, 22.07.2000, p. 5769-5772.

Research output: Contribution to journal › Article › Research › peer-review

TY - JOUR

T1 - A novel convergent approach to trans-fused polyether frameworks based on the reaction of vinylstannanes and triflates and its application to a synthetic study of the EFGH ring system of gambierol

AU - Kadowaki, Chie

AU - Chan, Philip W.H.

AU - Kadota, Isao

AU - Yamamoto, Yoshinori

PY - 2000/7/22

Y1 - 2000/7/22

N2 - A new strategy for the convergent assembly of six-membered polycyclic ether ring fragments has been developed based upon the novel reaction between vinylstannanes with triflates in the presence of a strong base. The application of the present method has allowed for a synthetic study of the EFGH ring of gambierol to be achieved. (C) 2000 Elsevier Science Ltd.

AB - A new strategy for the convergent assembly of six-membered polycyclic ether ring fragments has been developed based upon the novel reaction between vinylstannanes with triflates in the presence of a strong base. The application of the present method has allowed for a synthetic study of the EFGH ring of gambierol to be achieved. (C) 2000 Elsevier Science Ltd.

KW - Coupling

KW - Polycyclic ether

KW - Triflate

KW - Vinylstannane

UR - https://www.scopus.com/pages/publications/0034702516

U2 - 10.1016/S0040-4039(00)00952-7

DO - 10.1016/S0040-4039(00)00952-7

M3 - Article

AN - SCOPUS:0034702516

SN - 0040-4039

VL - 41

SP - 5769

EP - 5772

JO - Tetrahedron Letters

JF - Tetrahedron Letters

IS - 30

ER -

A novel convergent approach to trans-fused polyether frameworks based on the reaction of vinylstannanes and triflates and its application to a synthetic study of the EFGH ring system of gambierol

Abstract

Keywords

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