A novel convergent approach to trans-fused polyether frameworks based on the reaction of vinylstannanes and triflates and its application to a synthetic study of the EFGH ring system of gambierol

Chie Kadowaki, Philip W.H. Chan, Isao Kadota, Yoshinori Yamamoto

Research output: Contribution to journalArticleResearchpeer-review

35 Citations (Scopus)

Abstract

A new strategy for the convergent assembly of six-membered polycyclic ether ring fragments has been developed based upon the novel reaction between vinylstannanes with triflates in the presence of a strong base. The application of the present method has allowed for a synthetic study of the EFGH ring of gambierol to be achieved. (C) 2000 Elsevier Science Ltd.

Original languageEnglish
Pages (from-to)5769-5772
Number of pages4
JournalTetrahedron Letters
Volume41
Issue number30
DOIs
Publication statusPublished - 22 Jul 2000
Externally publishedYes

Keywords

  • Coupling
  • Polycyclic ether
  • Triflate
  • Vinylstannane

Cite this

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abstract = "A new strategy for the convergent assembly of six-membered polycyclic ether ring fragments has been developed based upon the novel reaction between vinylstannanes with triflates in the presence of a strong base. The application of the present method has allowed for a synthetic study of the EFGH ring of gambierol to be achieved. (C) 2000 Elsevier Science Ltd.",
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A novel convergent approach to trans-fused polyether frameworks based on the reaction of vinylstannanes and triflates and its application to a synthetic study of the EFGH ring system of gambierol. / Kadowaki, Chie; Chan, Philip W.H.; Kadota, Isao; Yamamoto, Yoshinori.

In: Tetrahedron Letters, Vol. 41, No. 30, 22.07.2000, p. 5769-5772.

Research output: Contribution to journalArticleResearchpeer-review

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AU - Kadowaki, Chie

AU - Chan, Philip W.H.

AU - Kadota, Isao

AU - Yamamoto, Yoshinori

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