A non-fullerene electron acceptor based on fluorene and diketopyrrolopyrrole building blocks for solution-processable organic solar cells with an impressive open-circuit voltage

Hemlata Patil; Xizu Wang; Akhil Gupta; Vijila Chellappan; Ante Bilic; Prashant Sonar; Anushri Rananaware; Sidhanath Vishwanath Bhosale; Sheshanath V Bhosale

doi:10.1039/c4cp03727h

A non-fullerene electron acceptor based on fluorene and diketopyrrolopyrrole building blocks for solution-processable organic solar cells with an impressive open-circuit voltage

Hemlata Patil, Xizu Wang, Akhil Gupta, Vijila Chellappan, Ante Bilic, Prashant Sonar, Anushri Rananaware, Sidhanath Vishwanath Bhosale, Sheshanath V Bhosale

Medicinal Chemistry

Research output: Contribution to journal › Article › Research › peer-review

59 Citations (Scopus)

Abstract

A novel solution-processable non-fullerene electron acceptor 6,6 -(5,5 -(9,9-dioctyl-9H-fluorene-2,7-diyl)bis(thiophene-5,2-diyl))bis(2,5-bis(2-ethylhexyl)-3-(thiophen-2-yl)pyrrolo[3,4-c]pyrrole-1,4(2H,5H)-dione) (DPP1) based on fluorene and diketopyrrolopyrrole conjugated moieties was designed, synthesized and fully characterized. DPP1 exhibited excellent solubility and high thermal stability which are essential for easy processing. Upon using DPP1 as an acceptor with the classical electron donor poly(3-hexylthiophene), solution processable bulk-heterojunction solar cells afforded a power conversion efficiency of 1.2 with a high open-circuit voltage (1.1 V). As per our knowledge, this value of open circuit voltage is one of the highest values reported so far for a bulk-heterojunction device using DPP1 as a non-fullerene acceptor.

Original language	English
Pages (from-to)	23837 - 23842
Number of pages	6
Journal	Physical Chemistry Chemical Physics
Volume	16
Issue number	43
DOIs	https://doi.org/10.1039/c4cp03727h
Publication status	Published - 2014

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Patil, H., Wang, X., Gupta, A., Chellappan, V., Bilic, A., Sonar, P., Rananaware, A., Bhosale, S. V., & Bhosale, S. V. (2014). A non-fullerene electron acceptor based on fluorene and diketopyrrolopyrrole building blocks for solution-processable organic solar cells with an impressive open-circuit voltage. Physical Chemistry Chemical Physics, 16(43), 23837 - 23842. https://doi.org/10.1039/c4cp03727h

Patil, Hemlata ; Wang, Xizu ; Gupta, Akhil ; Chellappan, Vijila ; Bilic, Ante ; Sonar, Prashant ; Rananaware, Anushri ; Bhosale, Sidhanath Vishwanath ; Bhosale, Sheshanath V. / A non-fullerene electron acceptor based on fluorene and diketopyrrolopyrrole building blocks for solution-processable organic solar cells with an impressive open-circuit voltage. In: Physical Chemistry Chemical Physics. 2014 ; Vol. 16, No. 43. pp. 23837 - 23842.

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title = "A non-fullerene electron acceptor based on fluorene and diketopyrrolopyrrole building blocks for solution-processable organic solar cells with an impressive open-circuit voltage",

abstract = "A novel solution-processable non-fullerene electron acceptor 6,6 -(5,5 -(9,9-dioctyl-9H-fluorene-2,7-diyl)bis(thiophene-5,2-diyl))bis(2,5-bis(2-ethylhexyl)-3-(thiophen-2-yl)pyrrolo[3,4-c]pyrrole-1,4(2H,5H)-dione) (DPP1) based on fluorene and diketopyrrolopyrrole conjugated moieties was designed, synthesized and fully characterized. DPP1 exhibited excellent solubility and high thermal stability which are essential for easy processing. Upon using DPP1 as an acceptor with the classical electron donor poly(3-hexylthiophene), solution processable bulk-heterojunction solar cells afforded a power conversion efficiency of 1.2 with a high open-circuit voltage (1.1 V). As per our knowledge, this value of open circuit voltage is one of the highest values reported so far for a bulk-heterojunction device using DPP1 as a non-fullerene acceptor.",

author = "Hemlata Patil and Xizu Wang and Akhil Gupta and Vijila Chellappan and Ante Bilic and Prashant Sonar and Anushri Rananaware and Bhosale, {Sidhanath Vishwanath} and Bhosale, {Sheshanath V}",

year = "2014",

doi = "10.1039/c4cp03727h",

language = "English",

volume = "16",

pages = "23837 -- 23842",

journal = "Physical Chemistry Chemical Physics",

issn = "1463-9076",

publisher = "The Royal Society of Chemistry",

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Patil, H, Wang, X, Gupta, A, Chellappan, V, Bilic, A, Sonar, P, Rananaware, A, Bhosale, SV & Bhosale, SV 2014, 'A non-fullerene electron acceptor based on fluorene and diketopyrrolopyrrole building blocks for solution-processable organic solar cells with an impressive open-circuit voltage', Physical Chemistry Chemical Physics, vol. 16, no. 43, pp. 23837 - 23842. https://doi.org/10.1039/c4cp03727h

A non-fullerene electron acceptor based on fluorene and diketopyrrolopyrrole building blocks for solution-processable organic solar cells with an impressive open-circuit voltage. / Patil, Hemlata; Wang, Xizu; Gupta, Akhil; Chellappan, Vijila; Bilic, Ante; Sonar, Prashant; Rananaware, Anushri; Bhosale, Sidhanath Vishwanath; Bhosale, Sheshanath V.

In: Physical Chemistry Chemical Physics, Vol. 16, No. 43, 2014, p. 23837 - 23842.

Research output: Contribution to journal › Article › Research › peer-review

TY - JOUR

T1 - A non-fullerene electron acceptor based on fluorene and diketopyrrolopyrrole building blocks for solution-processable organic solar cells with an impressive open-circuit voltage

AU - Patil, Hemlata

AU - Wang, Xizu

AU - Gupta, Akhil

AU - Chellappan, Vijila

AU - Bilic, Ante

AU - Sonar, Prashant

AU - Rananaware, Anushri

AU - Bhosale, Sidhanath Vishwanath

AU - Bhosale, Sheshanath V

PY - 2014

Y1 - 2014

N2 - A novel solution-processable non-fullerene electron acceptor 6,6 -(5,5 -(9,9-dioctyl-9H-fluorene-2,7-diyl)bis(thiophene-5,2-diyl))bis(2,5-bis(2-ethylhexyl)-3-(thiophen-2-yl)pyrrolo[3,4-c]pyrrole-1,4(2H,5H)-dione) (DPP1) based on fluorene and diketopyrrolopyrrole conjugated moieties was designed, synthesized and fully characterized. DPP1 exhibited excellent solubility and high thermal stability which are essential for easy processing. Upon using DPP1 as an acceptor with the classical electron donor poly(3-hexylthiophene), solution processable bulk-heterojunction solar cells afforded a power conversion efficiency of 1.2 with a high open-circuit voltage (1.1 V). As per our knowledge, this value of open circuit voltage is one of the highest values reported so far for a bulk-heterojunction device using DPP1 as a non-fullerene acceptor.

AB - A novel solution-processable non-fullerene electron acceptor 6,6 -(5,5 -(9,9-dioctyl-9H-fluorene-2,7-diyl)bis(thiophene-5,2-diyl))bis(2,5-bis(2-ethylhexyl)-3-(thiophen-2-yl)pyrrolo[3,4-c]pyrrole-1,4(2H,5H)-dione) (DPP1) based on fluorene and diketopyrrolopyrrole conjugated moieties was designed, synthesized and fully characterized. DPP1 exhibited excellent solubility and high thermal stability which are essential for easy processing. Upon using DPP1 as an acceptor with the classical electron donor poly(3-hexylthiophene), solution processable bulk-heterojunction solar cells afforded a power conversion efficiency of 1.2 with a high open-circuit voltage (1.1 V). As per our knowledge, this value of open circuit voltage is one of the highest values reported so far for a bulk-heterojunction device using DPP1 as a non-fullerene acceptor.

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U2 - 10.1039/c4cp03727h

DO - 10.1039/c4cp03727h

M3 - Article

VL - 16

SP - 23837

EP - 23842

JO - Physical Chemistry Chemical Physics

JF - Physical Chemistry Chemical Physics

SN - 1463-9076

IS - 43

ER -

A non-fullerene electron acceptor based on fluorene and diketopyrrolopyrrole building blocks for solution-processable organic solar cells with an impressive open-circuit voltage

Abstract

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