A new route to fluorocarbon-stabilized organoamidoplatinum(II) compounds-synthesis of a new isomer of [Pt(RNCH2CH2CH2NMe2)X(L)] (R = p-HC6F4 OR C6F5; X = Cl or I; L = unidentate ligand) complexes

D. P. Buxton, G. B. Deacon, Alison M. James, S. J. Knowles, Tracey L Williams

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Abstract

Reaction of the complexes PtX2(RNHCH2CH2NMe2) (X = Cl or I; R = p- HC6F4 or C6F5) with TIOR′ (R′ = Et or But) co-precipitates TlX and the organoamides [Pt(RNCH2CH2NMe2)X]2; these react with L (pyridine (py) or Me2SO) to give [Pt(NRCH2CH2NMe2)X(L)] complexes, which, in three cases (R = p-HC6F4 or C6F5, L = Me2SO, X =Cl; Cl; R = p-HC6F4, L = py, X = I), were obtained as the isomer with L trans to the NR group.

Original languageEnglish
Pages (from-to)2943-2945
Number of pages3
JournalPolyhedron
Volume8
Issue number24
DOIs
Publication statusPublished - 1989

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