TY - JOUR
T1 - A new method of synthesis of monomeric aryloxide complexes of manganese (II): Structures of manganese phenoxides
AU - Deacon, Glen Berenger
AU - Goh, Lai Yoong
AU - Jackson, William Roy
AU - Skelton, Brian W
AU - Chen, Wei
AU - White, Allan H
PY - 2010
Y1 - 2010
N2 - Monomeric manganese(II) complexes of bulky alkyl/arylsubstituted
phenoxides, [Mn C6HnRmO 2(DME)] [1: R = C6H5, n = 3,
m = 2 (2,6); 2: R = Me3C, n = 3, m = 2 (2,6); 3: R = Me3C, n = 2, m = 3 (2,4,6)] were prepared in yields of 37, 44 and 72 , respectively,from the reaction of manganese powder, Hg(C6F5)2 and the corresponding phenol in the presence of a little mercury in dimethoxyethane (DME). The compounds were characterized spectroscopically and by magnetic measurements. The single crystal structures of 1 and 3 and also of the mixed phenoxide complex [Mn (C6H3(C6H5)2-2,6-O C6H3(Me3C)2-2,6-O (DME)] 4 are reported.
AB - Monomeric manganese(II) complexes of bulky alkyl/arylsubstituted
phenoxides, [Mn C6HnRmO 2(DME)] [1: R = C6H5, n = 3,
m = 2 (2,6); 2: R = Me3C, n = 3, m = 2 (2,6); 3: R = Me3C, n = 2, m = 3 (2,4,6)] were prepared in yields of 37, 44 and 72 , respectively,from the reaction of manganese powder, Hg(C6F5)2 and the corresponding phenol in the presence of a little mercury in dimethoxyethane (DME). The compounds were characterized spectroscopically and by magnetic measurements. The single crystal structures of 1 and 3 and also of the mixed phenoxide complex [Mn (C6H3(C6H5)2-2,6-O C6H3(Me3C)2-2,6-O (DME)] 4 are reported.
UR - http://www3.interscience.wiley.com.ezproxy.lib.monash.edu.au/cgi-bin/fulltext/123388922/PDFSTART
U2 - 10.1002/zaac.201000021
DO - 10.1002/zaac.201000021
M3 - Article
VL - 636
SP - 1478
EP - 1483
JO - Zeitschrift fuer Anorganische und Allgemeine Chemie
JF - Zeitschrift fuer Anorganische und Allgemeine Chemie
SN - 0044-2313
IS - 8
ER -