A Highly Sensitive Diketopyrrolopyrrole-Based Ambipolar Transistor for Selective Detection and Discrimination of Xylene Isomers

Bin Wang; Tan Phat Huynh; Weiwei Wu; Naseem Hayek; Thu Trang Do; John C. Cancilla; Jose S. Torrecilla; Masrur Morshed Nahid; John M. Colwell; Oz M. Gazit; Sreenivasa Reddy Puniredd; Christopher R. McNeill; Prashant Sonar; Hossam Haick

doi:10.1002/adma.201505641

A Highly Sensitive Diketopyrrolopyrrole-Based Ambipolar Transistor for Selective Detection and Discrimination of Xylene Isomers

Bin Wang, Tan Phat Huynh, Weiwei Wu, Naseem Hayek, Thu Trang Do, John C. Cancilla, Jose S. Torrecilla, Masrur Morshed Nahid, John M. Colwell, Oz M. Gazit, Sreenivasa Reddy Puniredd, Christopher R. McNeill, Prashant Sonar, Hossam Haick

Materials Science & Engineering

Research output: Contribution to journal › Article › Research › peer-review

125 Citations (Scopus)

Abstract

A study is conducted to report here a sensor based on an ambipolar diketopyrrolopyrrole (DPP) copolymer fi eld-effect transistor (FET) to selectively and sensitively detect xylene isomers at 40 ppm, which is below the NIOSH long-term exposure limit for xylene isomers. The rationale behind this approach is that an ambipolar FET that can operate alternatively in n-channel and p-channel modes has been adopted for the generation of double-sensing parameters in hole and electron changes, rather than using a unipolar FET. An alternating copolymer, poly(diketopyrrolopyrrole-terthiophene) is synthesized by Stille coupling, using hexyldecyl-substituted DPP fl anked with thiophene.

Original language	English
Pages (from-to)	4012-4018
Number of pages	7
Journal	Advanced Materials
Volume	28
Issue number	21
DOIs	https://doi.org/10.1002/adma.201505641
Publication status	Published - 1 Jun 2016

Keywords

ambipolar
diketopyrrolopyrrole
isomers
sensors
xylene

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Wang, B., Huynh, T. P., Wu, W., Hayek, N., Do, T. T., Cancilla, J. C., Torrecilla, J. S., Nahid, M. M., Colwell, J. M., Gazit, O. M., Puniredd, S. R., McNeill, C. R., Sonar, P., & Haick, H. (2016). A Highly Sensitive Diketopyrrolopyrrole-Based Ambipolar Transistor for Selective Detection and Discrimination of Xylene Isomers. Advanced Materials, 28(21), 4012-4018. https://doi.org/10.1002/adma.201505641

@article{2518597f20644fcc91716cf3e0e0e092,

title = "A Highly Sensitive Diketopyrrolopyrrole-Based Ambipolar Transistor for Selective Detection and Discrimination of Xylene Isomers",

abstract = "A study is conducted to report here a sensor based on an ambipolar diketopyrrolopyrrole (DPP) copolymer fi eld-effect transistor (FET) to selectively and sensitively detect xylene isomers at 40 ppm, which is below the NIOSH long-term exposure limit for xylene isomers. The rationale behind this approach is that an ambipolar FET that can operate alternatively in n-channel and p-channel modes has been adopted for the generation of double-sensing parameters in hole and electron changes, rather than using a unipolar FET. An alternating copolymer, poly(diketopyrrolopyrrole-terthiophene) is synthesized by Stille coupling, using hexyldecyl-substituted DPP fl anked with thiophene.",

keywords = "ambipolar, diketopyrrolopyrrole, isomers, sensors, xylene",

author = "Bin Wang and Huynh, {Tan Phat} and Weiwei Wu and Naseem Hayek and Do, {Thu Trang} and Cancilla, {John C.} and Torrecilla, {Jose S.} and Nahid, {Masrur Morshed} and Colwell, {John M.} and Gazit, {Oz M.} and Puniredd, {Sreenivasa Reddy} and McNeill, {Christopher R.} and Prashant Sonar and Hossam Haick",

year = "2016",

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doi = "10.1002/adma.201505641",

language = "English",

volume = "28",

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journal = "Advanced Materials",

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Wang, B, Huynh, TP, Wu, W, Hayek, N, Do, TT, Cancilla, JC, Torrecilla, JS, Nahid, MM, Colwell, JM, Gazit, OM, Puniredd, SR, McNeill, CR, Sonar, P & Haick, H 2016, 'A Highly Sensitive Diketopyrrolopyrrole-Based Ambipolar Transistor for Selective Detection and Discrimination of Xylene Isomers', Advanced Materials, vol. 28, no. 21, pp. 4012-4018. https://doi.org/10.1002/adma.201505641

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T1 - A Highly Sensitive Diketopyrrolopyrrole-Based Ambipolar Transistor for Selective Detection and Discrimination of Xylene Isomers

AU - Wang, Bin

AU - Huynh, Tan Phat

AU - Wu, Weiwei

AU - Hayek, Naseem

AU - Do, Thu Trang

AU - Cancilla, John C.

AU - Torrecilla, Jose S.

AU - Nahid, Masrur Morshed

AU - Colwell, John M.

AU - Gazit, Oz M.

AU - Puniredd, Sreenivasa Reddy

AU - McNeill, Christopher R.

AU - Sonar, Prashant

AU - Haick, Hossam

PY - 2016/6/1

Y1 - 2016/6/1

N2 - A study is conducted to report here a sensor based on an ambipolar diketopyrrolopyrrole (DPP) copolymer fi eld-effect transistor (FET) to selectively and sensitively detect xylene isomers at 40 ppm, which is below the NIOSH long-term exposure limit for xylene isomers. The rationale behind this approach is that an ambipolar FET that can operate alternatively in n-channel and p-channel modes has been adopted for the generation of double-sensing parameters in hole and electron changes, rather than using a unipolar FET. An alternating copolymer, poly(diketopyrrolopyrrole-terthiophene) is synthesized by Stille coupling, using hexyldecyl-substituted DPP fl anked with thiophene.

AB - A study is conducted to report here a sensor based on an ambipolar diketopyrrolopyrrole (DPP) copolymer fi eld-effect transistor (FET) to selectively and sensitively detect xylene isomers at 40 ppm, which is below the NIOSH long-term exposure limit for xylene isomers. The rationale behind this approach is that an ambipolar FET that can operate alternatively in n-channel and p-channel modes has been adopted for the generation of double-sensing parameters in hole and electron changes, rather than using a unipolar FET. An alternating copolymer, poly(diketopyrrolopyrrole-terthiophene) is synthesized by Stille coupling, using hexyldecyl-substituted DPP fl anked with thiophene.

KW - ambipolar

KW - diketopyrrolopyrrole

KW - isomers

KW - sensors

KW - xylene

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JO - Advanced Materials

JF - Advanced Materials

IS - 21

ER -

A Highly Sensitive Diketopyrrolopyrrole-Based Ambipolar Transistor for Selective Detection and Discrimination of Xylene Isomers

Abstract

Keywords

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