A high nuclearity mixed valence {Mn32} complex

Stuart Langley, Rachel Stott, Nicholas Chilton, Boujemaa Moubaraki, Keith Murray

Research output: Contribution to journalArticleResearchpeer-review

38 Citations (Scopus)

Abstract

A mixed-valence Mn(32) complex, containing Mn(II), Mn(III) and Mn(IV) ions, with a probable S = 5 ground state, utilizes pivalate as a capping ligand and a variety of oxo-type bridging ligands. AC susceptibility data on fresh samples suggest that the Mn(32) complex is one of the largest nuclearity single molecule magnets found to date.
Original languageEnglish
Pages (from-to)6281 - 6283
Number of pages3
JournalChemical Communications
Volume47
Issue number22
DOIs
Publication statusPublished - 2011

Cite this