A high nuclearity mixed valence {Mn32} complex

Stuart Langley, Rachel Stott, Nicholas Chilton, Boujemaa Moubaraki, Keith Murray

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A mixed-valence Mn(32) complex, containing Mn(II), Mn(III) and Mn(IV) ions, with a probable S = 5 ground state, utilizes pivalate as a capping ligand and a variety of oxo-type bridging ligands. AC susceptibility data on fresh samples suggest that the Mn(32) complex is one of the largest nuclearity single molecule magnets found to date.
Original languageEnglish
Pages (from-to)6281 - 6283
Number of pages3
JournalChemical Communications
Issue number22
Publication statusPublished - 2011

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