A heterogeneous layered bifunctional catalyst for the integration of aerobic oxidation and asymmetric C-C bond formation

Hiroyuki Miyamura; Gerald C.Y. Choo; Tomohiro Yasukawa; Woo Jin Yoo; Shu Kobayashi

doi:10.1039/c3cc46204h

A heterogeneous layered bifunctional catalyst for the integration of aerobic oxidation and asymmetric C-C bond formation

Hiroyuki Miyamura, Gerald C.Y. Choo, Tomohiro Yasukawa, Woo Jin Yoo, Shu Kobayashi

Research output: Contribution to journal › Article › Research › peer-review

42 Citations (Scopus)

Abstract

The design and synthesis of a heterogeneous bifunctional chiral catalyst for the sequential aerobic oxidation-asymmetric Michael reactions between primary allylic alcohols and dibenzyl malonate are described. Interestingly, we found that layering bimetallic nanoparticles over the organocatalyst, within the chiral composite material, is crucial for catalytic activity.

Original language	English
Pages (from-to)	9917-9919
Number of pages	3
Journal	Chemical Communications
Volume	49
Issue number	85
DOIs	https://doi.org/10.1039/c3cc46204h
Publication status	Published - 4 Nov 2013
Externally published	Yes

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abstract = "The design and synthesis of a heterogeneous bifunctional chiral catalyst for the sequential aerobic oxidation-asymmetric Michael reactions between primary allylic alcohols and dibenzyl malonate are described. Interestingly, we found that layering bimetallic nanoparticles over the organocatalyst, within the chiral composite material, is crucial for catalytic activity.",

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AU - Yasukawa, Tomohiro

AU - Yoo, Woo Jin

AU - Kobayashi, Shu

PY - 2013/11/4

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AB - The design and synthesis of a heterogeneous bifunctional chiral catalyst for the sequential aerobic oxidation-asymmetric Michael reactions between primary allylic alcohols and dibenzyl malonate are described. Interestingly, we found that layering bimetallic nanoparticles over the organocatalyst, within the chiral composite material, is crucial for catalytic activity.

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JO - Chemical Communications

JF - Chemical Communications

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A heterogeneous layered bifunctional catalyst for the integration of aerobic oxidation and asymmetric C-C bond formation

Abstract

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