A functionalized Ag2S molecular architecture: facile assembly of the atomically precise ferrocene-decorated nanocluster [Ag74S19(dppp)6(fc(C{O}OCH2CH2S)2)18]

Yiyi Liu; Bahareh Khalili Najafabadi; Mahmood Azizpoor Fard; John F. Corrigan

doi:10.1002/anie.201411944

A functionalized Ag₂S molecular architecture: facile assembly of the atomically precise ferrocene-decorated nanocluster [Ag₇₄S₁₉(dppp)₆(fc(C{O}OCH₂CH₂S)₂)₁₈]

Yiyi Liu, Bahareh Khalili Najafabadi, Mahmood Azizpoor Fard, John F. Corrigan

Research output: Contribution to journal › Article › Research › peer-review

55 Citations (Scopus)

Abstract

A ferrocene-based dithiol 1,1′-[fc(C{O}OCH₂CH₂SH)₂] has been prepared and treated with a Ag^I salt to form the stable dithiolate compound [fc(C{O}OCH₂CH₂SAg)₂]_n (fc=[Fe(η⁵-C₅H₄)₂]). This is used as a reagent for the preparation of the nanocluster [Ag₇₄S₁₉(dppp)₆(fc(C{O}OCH₂CH₂S)₂)₁₈] which was obtained in good yield (dppp=1,3-bis(diphenylphosphino)propane).

Original language	English
Pages (from-to)	4832-4835
Number of pages	4
Journal	Angewandte Chemie - International Edition
Volume	54
Issue number	16
DOIs	https://doi.org/10.1002/anie.201411944
Publication status	Published - 13 Apr 2015
Externally published	Yes

Keywords

cluster compounds
iron
metallocenes
silver
structure elucidation

Access to Document

10.1002/anie.201411944

Cite this

@article{287111e348f545f9a37e3dd7657bd1e6,

title = "A functionalized Ag2S molecular architecture: facile assembly of the atomically precise ferrocene-decorated nanocluster [Ag74S19(dppp)6(fc(C{O}OCH2CH2S)2)18]",

abstract = "A ferrocene-based dithiol 1,1′-[fc(C{O}OCH2CH2SH)2] has been prepared and treated with a AgI salt to form the stable dithiolate compound [fc(C{O}OCH2CH2SAg)2]n (fc=[Fe(η5-C5H4)2]). This is used as a reagent for the preparation of the nanocluster [Ag74S19(dppp)6(fc(C{O}OCH2CH2S)2)18] which was obtained in good yield (dppp=1,3-bis(diphenylphosphino)propane).",

keywords = "cluster compounds, iron, metallocenes, silver, structure elucidation",

author = "Yiyi Liu and {Khalili Najafabadi}, Bahareh and {Azizpoor Fard}, Mahmood and Corrigan, {John F.}",

year = "2015",

month = apr,

day = "13",

doi = "10.1002/anie.201411944",

language = "English",

volume = "54",

pages = "4832--4835",

journal = "Angewandte Chemie - International Edition",

issn = "1433-7851",

publisher = "Wiley-Blackwell",

number = "16",

}

A functionalized Ag₂S molecular architecture: facile assembly of the atomically precise ferrocene-decorated nanocluster [Ag₇₄S₁₉(dppp)₆(fc(C{O}OCH₂CH₂S)₂)₁₈]. / Liu, Yiyi; Khalili Najafabadi, Bahareh; Azizpoor Fard, Mahmood et al.
In: Angewandte Chemie - International Edition, Vol. 54, No. 16, 13.04.2015, p. 4832-4835.

Research output: Contribution to journal › Article › Research › peer-review

TY - JOUR

T1 - A functionalized Ag2S molecular architecture

T2 - facile assembly of the atomically precise ferrocene-decorated nanocluster [Ag74S19(dppp)6(fc(C{O}OCH2CH2S)2)18]

AU - Liu, Yiyi

AU - Khalili Najafabadi, Bahareh

AU - Azizpoor Fard, Mahmood

AU - Corrigan, John F.

PY - 2015/4/13

Y1 - 2015/4/13

N2 - A ferrocene-based dithiol 1,1′-[fc(C{O}OCH2CH2SH)2] has been prepared and treated with a AgI salt to form the stable dithiolate compound [fc(C{O}OCH2CH2SAg)2]n (fc=[Fe(η5-C5H4)2]). This is used as a reagent for the preparation of the nanocluster [Ag74S19(dppp)6(fc(C{O}OCH2CH2S)2)18] which was obtained in good yield (dppp=1,3-bis(diphenylphosphino)propane).

AB - A ferrocene-based dithiol 1,1′-[fc(C{O}OCH2CH2SH)2] has been prepared and treated with a AgI salt to form the stable dithiolate compound [fc(C{O}OCH2CH2SAg)2]n (fc=[Fe(η5-C5H4)2]). This is used as a reagent for the preparation of the nanocluster [Ag74S19(dppp)6(fc(C{O}OCH2CH2S)2)18] which was obtained in good yield (dppp=1,3-bis(diphenylphosphino)propane).

KW - cluster compounds

KW - iron

KW - metallocenes

KW - silver

KW - structure elucidation

UR - http://www.scopus.com/inward/record.url?scp=85027957414&partnerID=8YFLogxK

U2 - 10.1002/anie.201411944

DO - 10.1002/anie.201411944

M3 - Article

C2 - 25703464

AN - SCOPUS:85027957414

SN - 1433-7851

VL - 54

SP - 4832

EP - 4835

JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

IS - 16