A functional hybrid polyoxometalate framework based on a ‘trilacunary’ heteropolyanion [(P4W6O34)2Co2Na2(H2O)2]18−

Chris Ritchie; Fengyan Li; Chullikkattil P. Pradeep; De Liang Long; Lin Xu; Leroy Cronin

doi:10.1039/b907410d

A functional hybrid polyoxometalate framework based on a ‘trilacunary’ heteropolyanion [(P₄W₆O₃₄)₂Co₂Na₂(H₂O)₂]¹⁸⁻

Chris Ritchie, Fengyan Li, Chullikkattil P. Pradeep, De Liang Long, Lin Xu, Leroy Cronin

Research output: Contribution to journal › Article › Research › peer-review

28 Citations (Scopus)

Abstract

Using multifunctional organocations a novel heteropolyanion, [(P₄W₆O₃₄)₂Co₂Na₂(H₂O)₂]¹⁸⁻, with unprecedented structural features, has been observed, and extension of these clusters from molecules into 1D chains occurs through a dimeric cobalt species, with this material exhibiting reversible colour/magnetic susceptibility changes upon dehydration.

Original language	English
Pages (from-to)	6483-6486
Number of pages	4
Journal	Dalton Transactions
Issue number	33
DOIs	https://doi.org/10.1039/b907410d
Publication status	Published - 11 Aug 2009
Externally published	Yes

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10.1039/b907410d

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abstract = "Using multifunctional organocations a novel heteropolyanion, [(P4W6O34)2Co2Na2(H2O)2]18−, with unprecedented structural features, has been observed, and extension of these clusters from molecules into 1D chains occurs through a dimeric cobalt species, with this material exhibiting reversible colour/magnetic susceptibility changes upon dehydration.",

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AU - Li, Fengyan

AU - Pradeep, Chullikkattil P.

AU - Long, De Liang

AU - Xu, Lin

AU - Cronin, Leroy

PY - 2009/8/11

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AB - Using multifunctional organocations a novel heteropolyanion, [(P4W6O34)2Co2Na2(H2O)2]18−, with unprecedented structural features, has been observed, and extension of these clusters from molecules into 1D chains occurs through a dimeric cobalt species, with this material exhibiting reversible colour/magnetic susceptibility changes upon dehydration.

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A functional hybrid polyoxometalate framework based on a ‘trilacunary’ heteropolyanion [(P4W6O34)2Co2Na2(H2O)2]18−

Abstract

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A functional hybrid polyoxometalate framework based on a ‘trilacunary’ heteropolyanion [(P₄W₆O₃₄)₂Co₂Na₂(H₂O)₂]¹⁸⁻