A fluoride bridged {CrIII4DyIII4} single molecule magnet

Stuart K Langley; Craig Macdonald Forsyth; Boujemaa Moubaraki; Keith Spencer Murray

doi:10.1039/c4dt03100h

A fluoride bridged {CrIII4DyIII4} single molecule magnet

Stuart K Langley, Craig Macdonald Forsyth, Boujemaa Moubaraki, Keith Spencer Murray

School of Chemistry

Research output: Contribution to journal › Article › Research › peer-review

35 Citations (Scopus)

Abstract

The synthesis of a heterometallic octanuclear CrIII 4DyIII 4 complex containing fluoride bridges displays SMM behaviour, with highly coercive magnetic hysteresis loops. Intriguingly multiple relaxation processes are revealed and the relaxation times are found to be longer compared to those of an analogous complex with the same metallic core topology.

Original language	English
Pages (from-to)	912 - 915
Number of pages	4
Journal	Dalton Transactions
Volume	44
Issue number	3
DOIs	https://doi.org/10.1039/c4dt03100h
Publication status	Published - 2015

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10.1039/c4dt03100h

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title = "A fluoride bridged {CrIII4DyIII4} single molecule magnet",

abstract = "The synthesis of a heterometallic octanuclear CrIII 4DyIII 4 complex containing fluoride bridges displays SMM behaviour, with highly coercive magnetic hysteresis loops. Intriguingly multiple relaxation processes are revealed and the relaxation times are found to be longer compared to those of an analogous complex with the same metallic core topology.",

author = "Langley, {Stuart K} and Forsyth, {Craig Macdonald} and Boujemaa Moubaraki and Murray, {Keith Spencer}",

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AU - Langley, Stuart K

AU - Forsyth, Craig Macdonald

AU - Moubaraki, Boujemaa

AU - Murray, Keith Spencer

PY - 2015

Y1 - 2015

N2 - The synthesis of a heterometallic octanuclear CrIII 4DyIII 4 complex containing fluoride bridges displays SMM behaviour, with highly coercive magnetic hysteresis loops. Intriguingly multiple relaxation processes are revealed and the relaxation times are found to be longer compared to those of an analogous complex with the same metallic core topology.

AB - The synthesis of a heterometallic octanuclear CrIII 4DyIII 4 complex containing fluoride bridges displays SMM behaviour, with highly coercive magnetic hysteresis loops. Intriguingly multiple relaxation processes are revealed and the relaxation times are found to be longer compared to those of an analogous complex with the same metallic core topology.

UR - http://pubs.rsc.org.ezproxy.lib.monash.edu.au/en/content/articlepdf/2015/dt/c4dt03100h

U2 - 10.1039/c4dt03100h

DO - 10.1039/c4dt03100h

M3 - Article

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VL - 44

SP - 912

EP - 915

JO - Dalton Transactions

JF - Dalton Transactions

IS - 3

ER -

A fluoride bridged {CrIII4DyIII4} single molecule magnet

Abstract

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Molecular Magnetic Materials of the Cluster and Network Types

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A fluoride bridged {CrIII4DyIII4} single molecule magnet

Abstract

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Molecular Magnetic Materials of the Cluster and Network Types

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