TY - JOUR
T1 - A facile method to synthesis a mesoporous carbon supported methanol catalyst containing well dispersed Cu/ZnO
AU - Duan, Huamei
AU - Yang, Yunxia
AU - Patel, Jim
AU - Dumbre, Deepa
AU - Bhargava, Suresh K.
AU - Burke, Nick R
AU - Zhai, Yuchun
AU - Webley, Paul A.
PY - 2014/12
Y1 - 2014/12
N2 - Alumina supported CuO/ZnO is the commercial catalyst for methanol synthesis from syngas. Though so far, this catalyst has been regarded as the dominant catalyst for methanol synthesis. The catalyst is still facing some fundamental challenges such as the dispersion of active center CuO/ZnO. Meanwhile, to prepare this catalyst, large amount of nitrate precursor was used and produced lots of environmentally harmful wastewater. In the current work, a bimodal carbon channel-confined CuO/ZnO supported on mesoporous carbon catalyst was synthesized by using a simple impregnation method followed by ammonia hydrolysis and pyrolysis. The results demonstrated that the method we developed was an effective way to control the dispersion of metal oxides particles.
AB - Alumina supported CuO/ZnO is the commercial catalyst for methanol synthesis from syngas. Though so far, this catalyst has been regarded as the dominant catalyst for methanol synthesis. The catalyst is still facing some fundamental challenges such as the dispersion of active center CuO/ZnO. Meanwhile, to prepare this catalyst, large amount of nitrate precursor was used and produced lots of environmentally harmful wastewater. In the current work, a bimodal carbon channel-confined CuO/ZnO supported on mesoporous carbon catalyst was synthesized by using a simple impregnation method followed by ammonia hydrolysis and pyrolysis. The results demonstrated that the method we developed was an effective way to control the dispersion of metal oxides particles.
KW - A. Structural materials
KW - B. Microstructure
KW - C. Transmission electron microscopy (TEM)
KW - D. Catalytic properties
UR - http://www.scopus.com/inward/record.url?scp=84907171295&partnerID=8YFLogxK
U2 - 10.1016/j.materresbull.2014.08.007
DO - 10.1016/j.materresbull.2014.08.007
M3 - Article
AN - SCOPUS:84907171295
SN - 0025-5408
VL - 60
SP - 232
EP - 237
JO - Materials Research Bulletin
JF - Materials Research Bulletin
ER -