A divalent heteroleptic lanthanoid fluoride complex stabilised by the tetraphenylcyclopentadienyl ligand, arising from C-F activation of pentafluorobenzene

Glen Berenger Deacon; Florian Jaroschik; Peter Courtney Junk; Rory Kelly

doi:10.1039/c4cc04427d

A divalent heteroleptic lanthanoid fluoride complex stabilised by the tetraphenylcyclopentadienyl ligand, arising from C-F activation of pentafluorobenzene

Glen Berenger Deacon, Florian Jaroschik, Peter Courtney Junk, Rory Kelly

School of Chemistry

Research output: Contribution to journal › Article › Research › peer-review

14 Citations (Scopus)

Abstract

The divalent heteroleptic lanthanoid fluoride complex, [Yb(C5Ph4H)(μ-F)(thf)2]2, as well as [Yb(C5Ph4H)2(thf)] and [Yb(C5Ph4H)(C6F5)(thf)2] were obtained from reactions of ytterbium metal with Hg(C6F5)2 and tetraphenylcyclopentadiene under different conditions, and C–F activation of C6F5H by Yb metal was observed.

Original language	English
Pages (from-to)	10655-10657
Number of pages	3
Journal	Chemical Communications
Volume	50
Issue number	73
DOIs	https://doi.org/10.1039/c4cc04427d
Publication status	Published - 21 Sep 2014

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10.1039/c4cc04427d

2520793-oaAccepted author manuscript, 740 KB

1 Finished

Advancing the chemistry of topical Rare Earth metals
Junk, P. C. & Mashima, K.
Australian Research Council (ARC), Monash University
3/01/13 → 31/12/15
Project: Research

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title = "A divalent heteroleptic lanthanoid fluoride complex stabilised by the tetraphenylcyclopentadienyl ligand, arising from C-F activation of pentafluorobenzene",

abstract = "The divalent heteroleptic lanthanoid fluoride complex, [Yb(C5Ph4H)(μ-F)(thf)2]2, as well as [Yb(C5Ph4H)2(thf)] and [Yb(C5Ph4H)(C6F5)(thf)2] were obtained from reactions of ytterbium metal with Hg(C6F5)2 and tetraphenylcyclopentadiene under different conditions, and C–F activation of C6F5H by Yb metal was observed.",

author = "Deacon, {Glen Berenger} and Florian Jaroschik and Junk, {Peter Courtney} and Rory Kelly",

year = "2014",

month = sep,

day = "21",

doi = "10.1039/c4cc04427d",

language = "English",

volume = "50",

pages = "10655--10657",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "The Royal Society of Chemistry",

number = "73",

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A divalent heteroleptic lanthanoid fluoride complex stabilised by the tetraphenylcyclopentadienyl ligand, arising from C-F activation of pentafluorobenzene. / Deacon, Glen Berenger; Jaroschik, Florian; Junk, Peter Courtney; Kelly, Rory.

In: Chemical Communications, Vol. 50, No. 73, 21.09.2014, p. 10655-10657.

Research output: Contribution to journal › Article › Research › peer-review

TY - JOUR

T1 - A divalent heteroleptic lanthanoid fluoride complex stabilised by the tetraphenylcyclopentadienyl ligand, arising from C-F activation of pentafluorobenzene

AU - Deacon, Glen Berenger

AU - Jaroschik, Florian

AU - Junk, Peter Courtney

AU - Kelly, Rory

PY - 2014/9/21

Y1 - 2014/9/21

N2 - The divalent heteroleptic lanthanoid fluoride complex, [Yb(C5Ph4H)(μ-F)(thf)2]2, as well as [Yb(C5Ph4H)2(thf)] and [Yb(C5Ph4H)(C6F5)(thf)2] were obtained from reactions of ytterbium metal with Hg(C6F5)2 and tetraphenylcyclopentadiene under different conditions, and C–F activation of C6F5H by Yb metal was observed.

AB - The divalent heteroleptic lanthanoid fluoride complex, [Yb(C5Ph4H)(μ-F)(thf)2]2, as well as [Yb(C5Ph4H)2(thf)] and [Yb(C5Ph4H)(C6F5)(thf)2] were obtained from reactions of ytterbium metal with Hg(C6F5)2 and tetraphenylcyclopentadiene under different conditions, and C–F activation of C6F5H by Yb metal was observed.

U2 - 10.1039/c4cc04427d

DO - 10.1039/c4cc04427d

M3 - Article

VL - 50

SP - 10655

EP - 10657

JO - Chemical Communications

JF - Chemical Communications

SN - 1359-7345

IS - 73

ER -

A divalent heteroleptic lanthanoid fluoride complex stabilised by the tetraphenylcyclopentadienyl ligand, arising from C-F activation of pentafluorobenzene

Abstract

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Advancing the chemistry of topical Rare Earth metals

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