A Deca-9-Fluorenolato-deca-Samarium Oxide Cage

Daniel Werner; Glen B. Deacon; Peter C. Junk

doi:10.1002/ejic.201800330

A Deca-9-Fluorenolato-deca-Samarium Oxide Cage

Daniel Werner, Glen B. Deacon, Peter C. Junk

School of Chemistry

Research output: Contribution to journal › Article › Research › peer-review

7 Citations (Scopus)

Abstract

The 9-fluorenone (fn) ketyl in [Yb^III(DippForm)₂(fn^·-O)] {DippForm = N,N′-bis(2,6-diisopropylphenyl)formamidinate}, underwent reduction to the dianion ({C₁₃H₈}-O) upon single electron transfer from Sm^III₂(thf)₂. The dianion was obtained as a decanuclear, deca-9-fluorenolato, tetraoxido mixed-oxidation-state samarium cage [Sm₁₀O₄{(C₁₃H₈)-O}₁₀(thf)₁₀], obtained after ligand redistribution. The structure is relevant to the deoxygenation of ketones by lanthanoid metals.

Original language	English
Pages (from-to)	2241-2246
Number of pages	6
Journal	European Journal of Inorganic Chemistry
Volume	2018
Issue number	20
DOIs	https://doi.org/10.1002/ejic.201800330
Publication status	Published - 7 Jun 2018

Keywords

Cage compounds
Cyclopentadienyl ligands
Ketones
Oxido ligands
Redox chemistry

Access to Document

10.1002/ejic.201800330

257365370-oaFinal published version, 2.06 MB

Cite this

@article{7a464862773745188538ff8e0ffc4290,

title = "A Deca-9-Fluorenolato-deca-Samarium Oxide Cage",

abstract = "The 9-fluorenone (fn) ketyl in [YbIII(DippForm)2(fn·-O)] \{DippForm = N,N′-bis(2,6-diisopropylphenyl)formamidinate\}, underwent reduction to the dianion (\{C13H8\}-O) upon single electron transfer from SmIII2(thf)2. The dianion was obtained as a decanuclear, deca-9-fluorenolato, tetraoxido mixed-oxidation-state samarium cage [Sm10O4\{(C13H8)-O\}10(thf)10], obtained after ligand redistribution. The structure is relevant to the deoxygenation of ketones by lanthanoid metals.",

keywords = "Cage compounds, Cyclopentadienyl ligands, Ketones, Oxido ligands, Redox chemistry",

author = "Daniel Werner and Deacon, \{Glen B.\} and Junk, \{Peter C.\}",

year = "2018",

month = jun,

day = "7",

doi = "10.1002/ejic.201800330",

language = "English",

volume = "2018",

pages = "2241--2246",

journal = "European Journal of Inorganic Chemistry",

issn = "1434-1948",

publisher = "Wiley-VCH Verlag GmbH \& Co. KGaA",

number = "20",

}

TY - JOUR

T1 - A Deca-9-Fluorenolato-deca-Samarium Oxide Cage

AU - Werner, Daniel

AU - Deacon, Glen B.

AU - Junk, Peter C.

PY - 2018/6/7

Y1 - 2018/6/7

N2 - The 9-fluorenone (fn) ketyl in [YbIII(DippForm)2(fn·-O)] {DippForm = N,N′-bis(2,6-diisopropylphenyl)formamidinate}, underwent reduction to the dianion ({C13H8}-O) upon single electron transfer from SmIII2(thf)2. The dianion was obtained as a decanuclear, deca-9-fluorenolato, tetraoxido mixed-oxidation-state samarium cage [Sm10O4{(C13H8)-O}10(thf)10], obtained after ligand redistribution. The structure is relevant to the deoxygenation of ketones by lanthanoid metals.

AB - The 9-fluorenone (fn) ketyl in [YbIII(DippForm)2(fn·-O)] {DippForm = N,N′-bis(2,6-diisopropylphenyl)formamidinate}, underwent reduction to the dianion ({C13H8}-O) upon single electron transfer from SmIII2(thf)2. The dianion was obtained as a decanuclear, deca-9-fluorenolato, tetraoxido mixed-oxidation-state samarium cage [Sm10O4{(C13H8)-O}10(thf)10], obtained after ligand redistribution. The structure is relevant to the deoxygenation of ketones by lanthanoid metals.

KW - Cage compounds

KW - Cyclopentadienyl ligands

KW - Ketones

KW - Oxido ligands

KW - Redox chemistry

UR - https://www.scopus.com/pages/publications/85048042153

U2 - 10.1002/ejic.201800330

DO - 10.1002/ejic.201800330

M3 - Article

AN - SCOPUS:85048042153

SN - 1434-1948

VL - 2018

SP - 2241

EP - 2246

JO - European Journal of Inorganic Chemistry

JF - European Journal of Inorganic Chemistry

IS - 20

ER -

A Deca-9-Fluorenolato-deca-Samarium Oxide Cage

Abstract

Keywords

Access to Document

Other files and links

Reactive metal-organics embracing the rare earth and alkaline earth metals

Cite this

A Deca-9-Fluorenolato-deca-Samarium Oxide Cage

Abstract

Keywords

Access to Document

Other files and links

Projects

Reactive metal-organics embracing the rare earth and alkaline earth metals

Cite this