A comparison of the NaOH-HCl and HCl-HF methods of extracting kerogen from two different marine oil shales

Jameel S. Aljariri Alhesan, Mohammad W. Amer, Marc Marshall, W. Roy Jackson, Thomas Gengenbach, Ying Qi, Martin L. Gorbaty, Peter J. Cassidy, Alan L. Chaffee

Research output: Contribution to journalArticleResearchpeer-review

Abstract

The organic matter (kerogen, defined as including the organic material soluble and insoluble in organic solvents at room temperature) from two marine oil shales, El-Lajjun (Jordan) and Julia Creek (Queensland, Australia), has been extracted by the commonly used HCl-HF method and the resulting products compared with those obtained using the NaOH-HCl method, i.e. with initial strong alkali extraction. The elemental analyses on a dry ash-free basis of the solids obtained by the two methods were similar to each other and to that of the original oil shale. The pyrolysis-gas chromatography–total ion chromatograms were also similar for the kerogens obtained by the two methods and for the original oil shale, showing regular n-alkene/alkane series, as would be expected from the high atomic H/C ratio, and series of alkyl substituted thiophenes and benzothiophenes. The solid state 13C NMR spectra showed similar trends. The Fe contents of the solids obtained by the HCl-HF treatment were much higher than for the solids from NaOH-HCl treatment, which could have implications for reactivity studies. XPS showed depletion of the sulfur and oxidation near the surface and confirmed that some aliphatic sulfur was present. However, in general, both methods gave organic products with similar characteristics, allowing isolation of organic matter by a method not involving HF, whose use is restricted in many countries.

Original languageEnglish
Pages (from-to)880-889
Number of pages10
JournalFuel
Volume236
DOIs
Publication statusPublished - 15 Jan 2019

Keywords

  • Elemental analysis
  • HCl-HF isolation method
  • NaOH-HCl isolation method
  • Oil shale kerogens
  • Pyrolysis-gas chromatography–mass spectrometry
  • Solid stateC NMR
  • XPS

Cite this

Aljariri Alhesan, Jameel S. ; Amer, Mohammad W. ; Marshall, Marc ; Jackson, W. Roy ; Gengenbach, Thomas ; Qi, Ying ; Gorbaty, Martin L. ; Cassidy, Peter J. ; Chaffee, Alan L. / A comparison of the NaOH-HCl and HCl-HF methods of extracting kerogen from two different marine oil shales. In: Fuel. 2019 ; Vol. 236. pp. 880-889.
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abstract = "The organic matter (kerogen, defined as including the organic material soluble and insoluble in organic solvents at room temperature) from two marine oil shales, El-Lajjun (Jordan) and Julia Creek (Queensland, Australia), has been extracted by the commonly used HCl-HF method and the resulting products compared with those obtained using the NaOH-HCl method, i.e. with initial strong alkali extraction. The elemental analyses on a dry ash-free basis of the solids obtained by the two methods were similar to each other and to that of the original oil shale. The pyrolysis-gas chromatography–total ion chromatograms were also similar for the kerogens obtained by the two methods and for the original oil shale, showing regular n-alkene/alkane series, as would be expected from the high atomic H/C ratio, and series of alkyl substituted thiophenes and benzothiophenes. The solid state 13C NMR spectra showed similar trends. The Fe contents of the solids obtained by the HCl-HF treatment were much higher than for the solids from NaOH-HCl treatment, which could have implications for reactivity studies. XPS showed depletion of the sulfur and oxidation near the surface and confirmed that some aliphatic sulfur was present. However, in general, both methods gave organic products with similar characteristics, allowing isolation of organic matter by a method not involving HF, whose use is restricted in many countries.",
keywords = "Elemental analysis, HCl-HF isolation method, NaOH-HCl isolation method, Oil shale kerogens, Pyrolysis-gas chromatography–mass spectrometry, Solid stateC NMR, XPS",
author = "{Aljariri Alhesan}, {Jameel S.} and Amer, {Mohammad W.} and Marc Marshall and Jackson, {W. Roy} and Thomas Gengenbach and Ying Qi and Gorbaty, {Martin L.} and Cassidy, {Peter J.} and Chaffee, {Alan L.}",
year = "2019",
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Aljariri Alhesan, JS, Amer, MW, Marshall, M, Jackson, WR, Gengenbach, T, Qi, Y, Gorbaty, ML, Cassidy, PJ & Chaffee, AL 2019, 'A comparison of the NaOH-HCl and HCl-HF methods of extracting kerogen from two different marine oil shales', Fuel, vol. 236, pp. 880-889. https://doi.org/10.1016/j.fuel.2018.09.058

A comparison of the NaOH-HCl and HCl-HF methods of extracting kerogen from two different marine oil shales. / Aljariri Alhesan, Jameel S.; Amer, Mohammad W.; Marshall, Marc; Jackson, W. Roy; Gengenbach, Thomas; Qi, Ying; Gorbaty, Martin L.; Cassidy, Peter J.; Chaffee, Alan L.

In: Fuel, Vol. 236, 15.01.2019, p. 880-889.

Research output: Contribution to journalArticleResearchpeer-review

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T1 - A comparison of the NaOH-HCl and HCl-HF methods of extracting kerogen from two different marine oil shales

AU - Aljariri Alhesan, Jameel S.

AU - Amer, Mohammad W.

AU - Marshall, Marc

AU - Jackson, W. Roy

AU - Gengenbach, Thomas

AU - Qi, Ying

AU - Gorbaty, Martin L.

AU - Cassidy, Peter J.

AU - Chaffee, Alan L.

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AB - The organic matter (kerogen, defined as including the organic material soluble and insoluble in organic solvents at room temperature) from two marine oil shales, El-Lajjun (Jordan) and Julia Creek (Queensland, Australia), has been extracted by the commonly used HCl-HF method and the resulting products compared with those obtained using the NaOH-HCl method, i.e. with initial strong alkali extraction. The elemental analyses on a dry ash-free basis of the solids obtained by the two methods were similar to each other and to that of the original oil shale. The pyrolysis-gas chromatography–total ion chromatograms were also similar for the kerogens obtained by the two methods and for the original oil shale, showing regular n-alkene/alkane series, as would be expected from the high atomic H/C ratio, and series of alkyl substituted thiophenes and benzothiophenes. The solid state 13C NMR spectra showed similar trends. The Fe contents of the solids obtained by the HCl-HF treatment were much higher than for the solids from NaOH-HCl treatment, which could have implications for reactivity studies. XPS showed depletion of the sulfur and oxidation near the surface and confirmed that some aliphatic sulfur was present. However, in general, both methods gave organic products with similar characteristics, allowing isolation of organic matter by a method not involving HF, whose use is restricted in many countries.

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