A butenolide intermediate in methylenomycin furan biosynthesis is implied by incorporation of stereospecifically 13C-labelled glycerols

Christophe Corre; Stuart W. Haynes; Nicolas Malet; Lijiang Song; Gregory L. Challis

doi:10.1039/c000496k

A butenolide intermediate in methylenomycin furan biosynthesis is implied by incorporation of stereospecifically 13C-labelled glycerols

Christophe Corre, Stuart W. Haynes, Nicolas Malet, Lijiang Song, Gregory L. Challis

Research output: Contribution to journal › Article › Research › peer-review

11 Citations (Scopus)

Abstract

The label from [3-¹³C]-l-glycerol is incorporated into the hydroxymethyl group of methylenomycin furans suggesting a butenolide intermediate in their biosynthesis.

Original language	English
Pages (from-to)	4079-4081
Number of pages	3
Journal	Chemical Communications
Volume	46
Issue number	23
DOIs	https://doi.org/10.1039/c000496k
Publication status	Published - 21 Jun 2010
Externally published	Yes

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title = "A butenolide intermediate in methylenomycin furan biosynthesis is implied by incorporation of stereospecifically 13C-labelled glycerols",

abstract = "The label from [3-13C]-l-glycerol is incorporated into the hydroxymethyl group of methylenomycin furans suggesting a butenolide intermediate in their biosynthesis.",

author = "Christophe Corre and Haynes, {Stuart W.} and Nicolas Malet and Lijiang Song and Challis, {Gregory L.}",

year = "2010",

month = jun,

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doi = "10.1039/c000496k",

language = "English",

volume = "46",

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journal = "Chemical Communications",

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T1 - A butenolide intermediate in methylenomycin furan biosynthesis is implied by incorporation of stereospecifically 13C-labelled glycerols

AU - Corre, Christophe

AU - Haynes, Stuart W.

AU - Malet, Nicolas

AU - Song, Lijiang

AU - Challis, Gregory L.

PY - 2010/6/21

Y1 - 2010/6/21

N2 - The label from [3-13C]-l-glycerol is incorporated into the hydroxymethyl group of methylenomycin furans suggesting a butenolide intermediate in their biosynthesis.

AB - The label from [3-13C]-l-glycerol is incorporated into the hydroxymethyl group of methylenomycin furans suggesting a butenolide intermediate in their biosynthesis.

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U2 - 10.1039/c000496k

DO - 10.1039/c000496k

M3 - Article

C2 - 20358097

AN - SCOPUS:77953190157

SN - 1359-7345

VL - 46

SP - 4079

EP - 4081

JO - Chemical Communications

JF - Chemical Communications

IS - 23

ER -

A butenolide intermediate in methylenomycin furan biosynthesis is implied by incorporation of stereospecifically 13C-labelled glycerols

Abstract

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