Abstract
In the title compound, C29H20F3NO 3S, the thia-zolidine ringadopts a half-chair conformation. The pyrrolidine and two five-membered carbocyclic rings are in envelope conformations with the spiro C atoms at the flaps. The trifluoro-methyl- substituted benzene ring forms dihedral angles of 62.37 (14) and 87.40 (14)° with the benzene rings of the dihydro-1H-indene units. The two benzene rings form a dihedral angle of 36.94 (15)°. The molecular structure is stabilized by intramolecular C - H⋯O hydrogen bonds, which generate S(6) ring motifs. In the crystal, molecules are linked into inversion dimers by pairs of intermolecular C - H⋯O hydrogen bonds, generating R2 2(10) ring motifs.
Original language | English |
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Pages (from-to) | o3293-o3294 |
Number of pages | 2 |
Journal | Acta Crystallographica Section E: Structure Reports Online |
Volume | 67 |
Issue number | 12 |
DOIs | |
Publication status | Published - Dec 2011 |
Externally published | Yes |
Keywords
- data-to-parameter ratio = 20.7
- mean σ(C-C) = 0.004 Å
- R factor = 0.063
- single-crystal X-ray study
- T = 296 K
- wR factor = 0.216