7′-(4-Bromophenyl)-5′,6′,7′,7a-tetrahydrodispiro- [Indan-2,5′-pyrrolo-[1,2-c][1,3]thiazole-6′,2″-Indan]-1,3, 1″-trione

Ang Chee Wei; Mohamed Ashraf Ali; Yeong Keng Yoon; Ching Kheng Quah; Hoong Kun Fun

doi:10.1107/S1600536811046514

7′-(4-Bromophenyl)-5′,6′,7′,7a-tetrahydrodispiro- [Indan-2,5′-pyrrolo-[1,2-c][1,3]thiazole-6′,2″-Indan]-1,3, 1″-trione

Ang Chee Wei, Mohamed Ashraf Ali, Yeong Keng Yoon, Ching Kheng Quah, Hoong Kun Fun

Research output: Contribution to journal › Article › Research › peer-review

3 Citations (Scopus)

Abstract

In the title compound, C₂₈H₂₀BrNO₃S, the thiazolidine, pyrrolidine and two five-membered carbocyclic rings are in envelope conformations. The bromo-bound phenyl ring forms dihedral angles of 61.97 (18) and 88.30 (17)°with the other two benzene rings. The two benzene rings form a dihedral angle of 30.3 (2)°. The molecular structure features an intramolecular C-H⋯O hydrogen bond, which generates an S(6) ring motif. In the crystal, molecules are linked into inversion dimers by pairs of C-H⋯O hydrogen bonds..

Original language	English
Pages (from-to)	o3274
Number of pages	1
Journal	Acta Crystallographica Section E: Structure Reports Online
Volume	67
Issue number	12
DOIs	https://doi.org/10.1107/S1600536811046514
Publication status	Published - Dec 2011
Externally published	Yes

Keywords

data-to-parameter ratio = 17.7
mean σ(C-C) = 0.005 Å
R factor = 0.044
single-crystal X-ray study
T = 296 K
wR factor = 0.136

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title = "7′-(4-Bromophenyl)-5′,6′,7′,7a-tetrahydrodispiro- [Indan-2,5′-pyrrolo-[1,2-c][1,3]thiazole-6′,2″-Indan]-1,3, 1″-trione",

abstract = "In the title compound, C28H20BrNO3S, the thiazolidine, pyrrolidine and two five-membered carbocyclic rings are in envelope conformations. The bromo-bound phenyl ring forms dihedral angles of 61.97 (18) and 88.30 (17)°with the other two benzene rings. The two benzene rings form a dihedral angle of 30.3 (2)°. The molecular structure features an intramolecular C-H⋯O hydrogen bond, which generates an S(6) ring motif. In the crystal, molecules are linked into inversion dimers by pairs of C-H⋯O hydrogen bonds..",

keywords = "data-to-parameter ratio = 17.7, mean σ(C-C) = 0.005 {\AA}, R factor = 0.044, single-crystal X-ray study, T = 296 K, wR factor = 0.136",

author = "Wei, {Ang Chee} and Ali, {Mohamed Ashraf} and Yoon, {Yeong Keng} and Quah, {Ching Kheng} and Fun, {Hoong Kun}",

year = "2011",

month = dec,

doi = "10.1107/S1600536811046514",

language = "English",

volume = "67",

pages = "o3274",

journal = "Acta Crystallographica Section E: Crystallographic Communications",

issn = "2056-9890",

publisher = "International Union of Crystallography (IUCr)",

number = "12",

}

7′-(4-Bromophenyl)-5′,6′,7′,7a-tetrahydrodispiro- [Indan-2,5′-pyrrolo-[1,2-c][1,3]thiazole-6′,2″-Indan]-1,3, 1″-trione. / Wei, Ang Chee; Ali, Mohamed Ashraf; Yoon, Yeong Keng et al.

In: Acta Crystallographica Section E: Structure Reports Online, Vol. 67, No. 12, 12.2011, p. o3274.

Research output: Contribution to journal › Article › Research › peer-review

TY - JOUR

T1 - 7′-(4-Bromophenyl)-5′,6′,7′,7a-tetrahydrodispiro- [Indan-2,5′-pyrrolo-[1,2-c][1,3]thiazole-6′,2″-Indan]-1,3, 1″-trione

AU - Wei, Ang Chee

AU - Ali, Mohamed Ashraf

AU - Yoon, Yeong Keng

AU - Quah, Ching Kheng

AU - Fun, Hoong Kun

PY - 2011/12

Y1 - 2011/12

N2 - In the title compound, C28H20BrNO3S, the thiazolidine, pyrrolidine and two five-membered carbocyclic rings are in envelope conformations. The bromo-bound phenyl ring forms dihedral angles of 61.97 (18) and 88.30 (17)°with the other two benzene rings. The two benzene rings form a dihedral angle of 30.3 (2)°. The molecular structure features an intramolecular C-H⋯O hydrogen bond, which generates an S(6) ring motif. In the crystal, molecules are linked into inversion dimers by pairs of C-H⋯O hydrogen bonds..

AB - In the title compound, C28H20BrNO3S, the thiazolidine, pyrrolidine and two five-membered carbocyclic rings are in envelope conformations. The bromo-bound phenyl ring forms dihedral angles of 61.97 (18) and 88.30 (17)°with the other two benzene rings. The two benzene rings form a dihedral angle of 30.3 (2)°. The molecular structure features an intramolecular C-H⋯O hydrogen bond, which generates an S(6) ring motif. In the crystal, molecules are linked into inversion dimers by pairs of C-H⋯O hydrogen bonds..

KW - data-to-parameter ratio = 17.7

KW - mean σ(C-C) = 0.005 Å

KW - R factor = 0.044

KW - single-crystal X-ray study

KW - T = 296 K

KW - wR factor = 0.136

UR - http://www.scopus.com/inward/record.url?scp=83155178472&partnerID=8YFLogxK

U2 - 10.1107/S1600536811046514

DO - 10.1107/S1600536811046514

M3 - Article

AN - SCOPUS:83155178472

VL - 67

SP - o3274

JO - Acta Crystallographica Section E: Crystallographic Communications

JF - Acta Crystallographica Section E: Crystallographic Communications

SN - 2056-9890

IS - 12

ER -

7′-(4-Bromophenyl)-5′,6′,7′,7a-tetrahydrodispiro- [Indan-2,5′-pyrrolo-[1,2-c][1,3]thiazole-6′,2″-Indan]-1,3, 1″-trione

Abstract

Keywords

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