7′-(2,5-Dimethoxyphenyl)-1′,3′,5′,6′, 7′,7a-hexahydrodispiro-[indan-2,5′-pyrrolo-[1,2-c][1,3] thiazole-6′,2″-indan]-1,3,1″-trione

Ang Chee Wei, Mohamed Ashraf Ali, Tan Soo Choon, Ibrahim Abdul Razak, Suhana Arshad

Research output: Contribution to journalArticleOtherpeer-review

3 Citations (Scopus)

Abstract

In the title compound, C 30H 25NO 5S, all the five-membered rings are in envelope conformations with the spiro and methylene C atoms as the flap atoms. Intramolecular C - H⋯O interactions stabilize the molecular structure and form S(6) and S(7) ring motifs. The mean plane through the hexahydropyrrolo-[1,2-c]thiazole ring [r.m.s deviation of 0.0393 (1) Å] makes dihedral angles of 60.92 (5), 88.33 (4) and 84.12 (4)° with the terminal benzene ring and the mean planes of the mono and dioxo substituted indan rings, respectively. molecules are linked by inter-molecular C - H⋯O inter-actions into a three-dimensional network. In addition, C - H⋯π and π-π interactions [centroid-to-centroid distance = 3.4084 (8) Å] further stabilize the crystal structure.

Original languageEnglish
Pages (from-to)o560-o561
Number of pages2
JournalActa Crystallographica Section E: Structure Reports Online
Volume68
Issue number3
DOIs
Publication statusPublished - Mar 2012
Externally publishedYes

Keywords

  • data-to-parameter ratio = 22.5
  • mean σ(C-C) = 0.002 Å
  • R factor = 0.038
  • single-crystal X-ray study
  • T = 100 K
  • wR factor = 0.106

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