Abstract
In the title compound, C 30H 25NO 5S, all the five-membered rings are in envelope conformations with the spiro and methylene C atoms as the flap atoms. Intramolecular C - H⋯O interactions stabilize the molecular structure and form S(6) and S(7) ring motifs. The mean plane through the hexahydropyrrolo-[1,2-c]thiazole ring [r.m.s deviation of 0.0393 (1) Å] makes dihedral angles of 60.92 (5), 88.33 (4) and 84.12 (4)° with the terminal benzene ring and the mean planes of the mono and dioxo substituted indan rings, respectively. molecules are linked by inter-molecular C - H⋯O inter-actions into a three-dimensional network. In addition, C - H⋯π and π-π interactions [centroid-to-centroid distance = 3.4084 (8) Å] further stabilize the crystal structure.
Original language | English |
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Pages (from-to) | o560-o561 |
Number of pages | 2 |
Journal | Acta Crystallographica Section E: Structure Reports Online |
Volume | 68 |
Issue number | 3 |
DOIs | |
Publication status | Published - Mar 2012 |
Externally published | Yes |
Keywords
- data-to-parameter ratio = 22.5
- mean σ(C-C) = 0.002 Å
- R factor = 0.038
- single-crystal X-ray study
- T = 100 K
- wR factor = 0.106