TY - JOUR
T1 - 4′-(4-Bromophenyl)-1′-methyldispiro-[acenaphthylene-1, 2′-pyrrolidine-3′,2′′-indane]-2,1′′(1H) -dione
AU - Wei, Ang Chee
AU - Ali, Mohamed Ashraf
AU - Choon, Tan Soo
AU - Arshad, Suhana
AU - Razak, Ibrahim Abdul
N1 - Copyright:
Copyright 2012 Elsevier B.V., All rights reserved.
PY - 2012/5
Y1 - 2012/5
N2 - In the title compound, C30H22BrNO2, the cyclo-pentane ring of the dihydro-acenaphthyl-ene group and the pyrrolidine ring are both in envelope conformations with the spiro C atom and N atom, respectively, as the flap atom. The cyclo-pentane ring of the indane group adopts a half-chair conformation. A weak intra-molecular C - H⋯O hydrogen bond forms an S(8) ring motif. The naphthalene ring system of the dihydro-acenaphthyl-ene group forms dihedral angles of 41.76 (6) and 42.17 (6)°with the benzene ring of the bromo-phenyl group and the benzene ring of the indane group, respectively. The dihedral angle between the two benzene rings is 83.92 (7)°. In the crystal, molecules are linked by weak C - H⋯O and C - H⋯N hydrogen bonds into a two-dimensional network parallel to the ac plane. Weak C - H⋯π inter-actions are also observed.
AB - In the title compound, C30H22BrNO2, the cyclo-pentane ring of the dihydro-acenaphthyl-ene group and the pyrrolidine ring are both in envelope conformations with the spiro C atom and N atom, respectively, as the flap atom. The cyclo-pentane ring of the indane group adopts a half-chair conformation. A weak intra-molecular C - H⋯O hydrogen bond forms an S(8) ring motif. The naphthalene ring system of the dihydro-acenaphthyl-ene group forms dihedral angles of 41.76 (6) and 42.17 (6)°with the benzene ring of the bromo-phenyl group and the benzene ring of the indane group, respectively. The dihedral angle between the two benzene rings is 83.92 (7)°. In the crystal, molecules are linked by weak C - H⋯O and C - H⋯N hydrogen bonds into a two-dimensional network parallel to the ac plane. Weak C - H⋯π inter-actions are also observed.
UR - https://www.scopus.com/pages/publications/84860712079
U2 - 10.1107/S1600536812014213
DO - 10.1107/S1600536812014213
M3 - Article
AN - SCOPUS:84860712079
SN - 2056-9890
VL - 68
SP - o1340-o1341
JO - Acta Crystallographica Section E: Structure Reports Online
JF - Acta Crystallographica Section E: Structure Reports Online
IS - 5
ER -