2D and 3D Coordination Networks of Polynuclear Bismuth Oxido/Hydroxido Sulfonato Clusters from Low Temperature Solid-State Metathesis Reactions

Dimuthu C. Senevirathna; Melissa V. Werrett; Victoria L. Blair; Michael Mehring; Philip C. Andrews

doi:10.1002/chem.201705981

2D and 3D Coordination Networks of Polynuclear Bismuth Oxido/Hydroxido Sulfonato Clusters from Low Temperature Solid-State Metathesis Reactions

Dimuthu C. Senevirathna, Melissa V. Werrett, Victoria L. Blair, Michael Mehring, Philip C. Andrews

School of Chemistry

Research output: Contribution to journal › Article › Research › peer-review

8 Citations (Scopus)

Abstract

Solid-state metathesis (SSM) reactions between Bi(NO₃)₃⋅5 H₂O and potassium benzene-1,2-disulfonate (=1,2-BDSK₂), sodium benzene-1,3-disulfonate (=1,3-BDSNa₂) allows access to the first 2D, {[Bi₆O₄(OH)₄(1–2BDS)₂(NO₃)₂⋅4 H₂O]⋅11 H₂O}_∞ and {[Bi₂₂O₂₄(OH)₆(1,3-BDS)₆⋅12 DMSO]⋅3 DMSO⋅4 H₂O}_∞, and 3D, {[Bi₆O₄(OH)₄(1,3-BDS)₃⋅4 H₂O]⋅6 H₂O}_∞, polymeric networks of sulfonato encapsulated polynuclear bismuth oxido/hydroxido clusters.

Original language	English
Pages (from-to)	6722-6726
Number of pages	5
Journal	Chemistry - A European Journal
Volume	24
Issue number	26
DOIs	https://doi.org/10.1002/chem.201705981
Publication status	Published - 7 May 2018

Keywords

bismuth
oxido clusters
polymeric networks
solid-state metathesis
structure elucidation

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10.1002/chem.201705981

Cite this

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title = "2D and 3D Coordination Networks of Polynuclear Bismuth Oxido/Hydroxido Sulfonato Clusters from Low Temperature Solid-State Metathesis Reactions",

abstract = "Solid-state metathesis (SSM) reactions between Bi(NO3)3⋅5 H2O and potassium benzene-1,2-disulfonate (=1,2-BDSK2), sodium benzene-1,3-disulfonate (=1,3-BDSNa2) allows access to the first 2D, {[Bi6O4(OH)4(1–2BDS)2(NO3)2⋅4 H2O]⋅11 H2O}∞ and {[Bi22O24(OH)6(1,3-BDS)6⋅12 DMSO]⋅3 DMSO⋅4 H2O}∞, and 3D, {[Bi6O4(OH)4(1,3-BDS)3⋅4 H2O]⋅6 H2O}∞, polymeric networks of sulfonato encapsulated polynuclear bismuth oxido/hydroxido clusters.",

keywords = "bismuth, oxido clusters, polymeric networks, solid-state metathesis, structure elucidation",

author = "Senevirathna, {Dimuthu C.} and Werrett, {Melissa V.} and Blair, {Victoria L.} and Michael Mehring and Andrews, {Philip C.}",

year = "2018",

month = may,

day = "7",

doi = "10.1002/chem.201705981",

language = "English",

volume = "24",

pages = "6722--6726",

journal = "Chemistry - A European Journal",

issn = "1521-3765",

publisher = "Wiley-VCH Verlag GmbH & Co. KGaA",

number = "26",

}

2D and 3D Coordination Networks of Polynuclear Bismuth Oxido/Hydroxido Sulfonato Clusters from Low Temperature Solid-State Metathesis Reactions. / Senevirathna, Dimuthu C.; Werrett, Melissa V.; Blair, Victoria L.; Mehring, Michael; Andrews, Philip C.

In: Chemistry - A European Journal, Vol. 24, No. 26, 07.05.2018, p. 6722-6726.

Research output: Contribution to journal › Article › Research › peer-review

TY - JOUR

T1 - 2D and 3D Coordination Networks of Polynuclear Bismuth Oxido/Hydroxido Sulfonato Clusters from Low Temperature Solid-State Metathesis Reactions

AU - Senevirathna, Dimuthu C.

AU - Werrett, Melissa V.

AU - Blair, Victoria L.

AU - Mehring, Michael

AU - Andrews, Philip C.

PY - 2018/5/7

Y1 - 2018/5/7

N2 - Solid-state metathesis (SSM) reactions between Bi(NO3)3⋅5 H2O and potassium benzene-1,2-disulfonate (=1,2-BDSK2), sodium benzene-1,3-disulfonate (=1,3-BDSNa2) allows access to the first 2D, {[Bi6O4(OH)4(1–2BDS)2(NO3)2⋅4 H2O]⋅11 H2O}∞ and {[Bi22O24(OH)6(1,3-BDS)6⋅12 DMSO]⋅3 DMSO⋅4 H2O}∞, and 3D, {[Bi6O4(OH)4(1,3-BDS)3⋅4 H2O]⋅6 H2O}∞, polymeric networks of sulfonato encapsulated polynuclear bismuth oxido/hydroxido clusters.

AB - Solid-state metathesis (SSM) reactions between Bi(NO3)3⋅5 H2O and potassium benzene-1,2-disulfonate (=1,2-BDSK2), sodium benzene-1,3-disulfonate (=1,3-BDSNa2) allows access to the first 2D, {[Bi6O4(OH)4(1–2BDS)2(NO3)2⋅4 H2O]⋅11 H2O}∞ and {[Bi22O24(OH)6(1,3-BDS)6⋅12 DMSO]⋅3 DMSO⋅4 H2O}∞, and 3D, {[Bi6O4(OH)4(1,3-BDS)3⋅4 H2O]⋅6 H2O}∞, polymeric networks of sulfonato encapsulated polynuclear bismuth oxido/hydroxido clusters.

KW - bismuth

KW - oxido clusters

KW - polymeric networks

KW - solid-state metathesis

KW - structure elucidation

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DO - 10.1002/chem.201705981

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VL - 24

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EP - 6726

JO - Chemistry - A European Journal

JF - Chemistry - A European Journal

SN - 1521-3765

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ER -

2D and 3D Coordination Networks of Polynuclear Bismuth Oxido/Hydroxido Sulfonato Clusters from Low Temperature Solid-State Metathesis Reactions

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Targeting Bio-Compatible Homo- and Hetero-bimetallic Cages and their Application in High Energy and Dual Energy Computed Tomography

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2D and 3D Coordination Networks of Polynuclear Bismuth Oxido/Hydroxido Sulfonato Clusters from Low Temperature Solid-State Metathesis Reactions

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Keywords

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Targeting Bio-Compatible Homo- and Hetero-bimetallic Cages and their Application in High Energy and Dual Energy Computed Tomography

Advanced in-situ electron microscope facility for research in alloys, nanomaterials, functional materials, magnetic materials and minerals

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Australian Synchrotron

X-ray Platform (MXP)

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