2D and 3D Coordination Networks of Polynuclear Bismuth Oxido/Hydroxido Sulfonato Clusters from Low Temperature Solid-State Metathesis Reactions

Dimuthu C. Senevirathna, Melissa V. Werrett, Victoria L. Blair, Michael Mehring, Philip C. Andrews

Research output: Contribution to journalArticleResearchpeer-review

Abstract

Solid-state metathesis (SSM) reactions between Bi(NO3)3⋅5 H2O and potassium benzene-1,2-disulfonate (=1,2-BDSK2), sodium benzene-1,3-disulfonate (=1,3-BDSNa2) allows access to the first 2D, {[Bi6O4(OH)4(1–2BDS)2(NO3)2⋅4 H2O]⋅11 H2O} and {[Bi22O24(OH)6(1,3-BDS)6⋅12 DMSO]⋅3 DMSO⋅4 H2O}, and 3D, {[Bi6O4(OH)4(1,3-BDS)3⋅4 H2O]⋅6 H2O}, polymeric networks of sulfonato encapsulated polynuclear bismuth oxido/hydroxido clusters.

Original languageEnglish
Pages (from-to)6722-6726
Number of pages5
JournalChemistry - A European Journal
Volume24
Issue number26
DOIs
Publication statusPublished - 7 May 2018

Keywords

  • bismuth
  • oxido clusters
  • polymeric networks
  • solid-state metathesis
  • structure elucidation

Cite this

@article{5e818735121d41beb1d374aabf49fb8e,
title = "2D and 3D Coordination Networks of Polynuclear Bismuth Oxido/Hydroxido Sulfonato Clusters from Low Temperature Solid-State Metathesis Reactions",
abstract = "Solid-state metathesis (SSM) reactions between Bi(NO3)3⋅5 H2O and potassium benzene-1,2-disulfonate (=1,2-BDSK2), sodium benzene-1,3-disulfonate (=1,3-BDSNa2) allows access to the first 2D, {[Bi6O4(OH)4(1–2BDS)2(NO3)2⋅4 H2O]⋅11 H2O}∞ and {[Bi22O24(OH)6(1,3-BDS)6⋅12 DMSO]⋅3 DMSO⋅4 H2O}∞, and 3D, {[Bi6O4(OH)4(1,3-BDS)3⋅4 H2O]⋅6 H2O}∞, polymeric networks of sulfonato encapsulated polynuclear bismuth oxido/hydroxido clusters.",
keywords = "bismuth, oxido clusters, polymeric networks, solid-state metathesis, structure elucidation",
author = "Senevirathna, {Dimuthu C.} and Werrett, {Melissa V.} and Blair, {Victoria L.} and Michael Mehring and Andrews, {Philip C.}",
year = "2018",
month = "5",
day = "7",
doi = "10.1002/chem.201705981",
language = "English",
volume = "24",
pages = "6722--6726",
journal = "Chemistry - A European Journal",
issn = "1521-3765",
publisher = "Wiley-VCH Verlag GmbH & Co. KGaA",
number = "26",

}

2D and 3D Coordination Networks of Polynuclear Bismuth Oxido/Hydroxido Sulfonato Clusters from Low Temperature Solid-State Metathesis Reactions. / Senevirathna, Dimuthu C.; Werrett, Melissa V.; Blair, Victoria L.; Mehring, Michael; Andrews, Philip C.

In: Chemistry - A European Journal, Vol. 24, No. 26, 07.05.2018, p. 6722-6726.

Research output: Contribution to journalArticleResearchpeer-review

TY - JOUR

T1 - 2D and 3D Coordination Networks of Polynuclear Bismuth Oxido/Hydroxido Sulfonato Clusters from Low Temperature Solid-State Metathesis Reactions

AU - Senevirathna, Dimuthu C.

AU - Werrett, Melissa V.

AU - Blair, Victoria L.

AU - Mehring, Michael

AU - Andrews, Philip C.

PY - 2018/5/7

Y1 - 2018/5/7

N2 - Solid-state metathesis (SSM) reactions between Bi(NO3)3⋅5 H2O and potassium benzene-1,2-disulfonate (=1,2-BDSK2), sodium benzene-1,3-disulfonate (=1,3-BDSNa2) allows access to the first 2D, {[Bi6O4(OH)4(1–2BDS)2(NO3)2⋅4 H2O]⋅11 H2O}∞ and {[Bi22O24(OH)6(1,3-BDS)6⋅12 DMSO]⋅3 DMSO⋅4 H2O}∞, and 3D, {[Bi6O4(OH)4(1,3-BDS)3⋅4 H2O]⋅6 H2O}∞, polymeric networks of sulfonato encapsulated polynuclear bismuth oxido/hydroxido clusters.

AB - Solid-state metathesis (SSM) reactions between Bi(NO3)3⋅5 H2O and potassium benzene-1,2-disulfonate (=1,2-BDSK2), sodium benzene-1,3-disulfonate (=1,3-BDSNa2) allows access to the first 2D, {[Bi6O4(OH)4(1–2BDS)2(NO3)2⋅4 H2O]⋅11 H2O}∞ and {[Bi22O24(OH)6(1,3-BDS)6⋅12 DMSO]⋅3 DMSO⋅4 H2O}∞, and 3D, {[Bi6O4(OH)4(1,3-BDS)3⋅4 H2O]⋅6 H2O}∞, polymeric networks of sulfonato encapsulated polynuclear bismuth oxido/hydroxido clusters.

KW - bismuth

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