Abstract
Solid-state metathesis (SSM) reactions between Bi(NO3)3⋅5 H2O and potassium benzene-1,2-disulfonate (=1,2-BDSK2), sodium benzene-1,3-disulfonate (=1,3-BDSNa2) allows access to the first 2D, {[Bi6O4(OH)4(1–2BDS)2(NO3)2⋅4 H2O]⋅11 H2O}∞ and {[Bi22O24(OH)6(1,3-BDS)6⋅12 DMSO]⋅3 DMSO⋅4 H2O}∞, and 3D, {[Bi6O4(OH)4(1,3-BDS)3⋅4 H2O]⋅6 H2O}∞, polymeric networks of sulfonato encapsulated polynuclear bismuth oxido/hydroxido clusters.
| Original language | English |
|---|---|
| Pages (from-to) | 6722-6726 |
| Number of pages | 5 |
| Journal | Chemistry - A European Journal |
| Volume | 24 |
| Issue number | 26 |
| DOIs | |
| Publication status | Published - 7 May 2018 |
Keywords
- bismuth
- oxido clusters
- polymeric networks
- solid-state metathesis
- structure elucidation
Cite this
}
2D and 3D Coordination Networks of Polynuclear Bismuth Oxido/Hydroxido Sulfonato Clusters from Low Temperature Solid-State Metathesis Reactions. / Senevirathna, Dimuthu C.; Werrett, Melissa V.; Blair, Victoria L.; Mehring, Michael; Andrews, Philip C.
In: Chemistry - A European Journal, Vol. 24, No. 26, 07.05.2018, p. 6722-6726.Research output: Contribution to journal › Article › Research › peer-review
TY - JOUR
T1 - 2D and 3D Coordination Networks of Polynuclear Bismuth Oxido/Hydroxido Sulfonato Clusters from Low Temperature Solid-State Metathesis Reactions
AU - Senevirathna, Dimuthu C.
AU - Werrett, Melissa V.
AU - Blair, Victoria L.
AU - Mehring, Michael
AU - Andrews, Philip C.
PY - 2018/5/7
Y1 - 2018/5/7
N2 - Solid-state metathesis (SSM) reactions between Bi(NO3)3⋅5 H2O and potassium benzene-1,2-disulfonate (=1,2-BDSK2), sodium benzene-1,3-disulfonate (=1,3-BDSNa2) allows access to the first 2D, {[Bi6O4(OH)4(1–2BDS)2(NO3)2⋅4 H2O]⋅11 H2O}∞ and {[Bi22O24(OH)6(1,3-BDS)6⋅12 DMSO]⋅3 DMSO⋅4 H2O}∞, and 3D, {[Bi6O4(OH)4(1,3-BDS)3⋅4 H2O]⋅6 H2O}∞, polymeric networks of sulfonato encapsulated polynuclear bismuth oxido/hydroxido clusters.
AB - Solid-state metathesis (SSM) reactions between Bi(NO3)3⋅5 H2O and potassium benzene-1,2-disulfonate (=1,2-BDSK2), sodium benzene-1,3-disulfonate (=1,3-BDSNa2) allows access to the first 2D, {[Bi6O4(OH)4(1–2BDS)2(NO3)2⋅4 H2O]⋅11 H2O}∞ and {[Bi22O24(OH)6(1,3-BDS)6⋅12 DMSO]⋅3 DMSO⋅4 H2O}∞, and 3D, {[Bi6O4(OH)4(1,3-BDS)3⋅4 H2O]⋅6 H2O}∞, polymeric networks of sulfonato encapsulated polynuclear bismuth oxido/hydroxido clusters.
KW - bismuth
KW - oxido clusters
KW - polymeric networks
KW - solid-state metathesis
KW - structure elucidation
UR - http://www.scopus.com/inward/record.url?scp=85045742358&partnerID=8YFLogxK
U2 - 10.1002/chem.201705981
DO - 10.1002/chem.201705981
M3 - Article
VL - 24
SP - 6722
EP - 6726
JO - Chemistry - A European Journal
JF - Chemistry - A European Journal
SN - 1521-3765
IS - 26
ER -