2,4,6‐Tri(4‐pyridyl)‐1,3,5‐triazine as a 3‐Connecting Building Block for Infinite Nets

Stuart R. Batten; Bernard F. Hoskins; Richard Robson

doi:10.1002/anie.199508201

2,4,6‐Tri(4‐pyridyl)‐1,3,5‐triazine as a 3‐Connecting Building Block for Infinite Nets

Stuart R. Batten, Bernard F. Hoskins, Richard Robson

Research output: Contribution to journal › Article › Research › peer-review

111 Citations (Scopus)

Abstract

A new three‐dimensional coordination network with cubic symmetry is displayed by the structure of 1 (shown on the right). Compound 1 is obtained from tri(4‐pyridyl)triazine ligands (tpt) and Hg²⁺ ions, and has a system of interconnected spacious cavities which are occupied by large numbers of solvent molecules and counterions. The coordination sphere of the Hg center is formed by six pyridine substituents, which is very rare for complexes. (Formula Presented.) (Figure Presented.)

Original language	English
Pages (from-to)	820-822
Number of pages	3
Journal	Angewandte Chemie: International Edition in English
Volume	34
Issue number	7
DOIs	https://doi.org/10.1002/anie.199508201
Publication status	Published - 13 Apr 1995
Externally published	Yes

Keywords

complexes with nitrogen ligands
mercury compounds
networks
triazines

Access to Document

10.1002/anie.199508201

Link to publication in Scopus

Cite this

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title = "2,4,6‐Tri(4‐pyridyl)‐1,3,5‐triazine as a 3‐Connecting Building Block for Infinite Nets",

abstract = "A new three‐dimensional coordination network with cubic symmetry is displayed by the structure of 1 (shown on the right). Compound 1 is obtained from tri(4‐pyridyl)triazine ligands (tpt) and Hg2+ ions, and has a system of interconnected spacious cavities which are occupied by large numbers of solvent molecules and counterions. The coordination sphere of the Hg center is formed by six pyridine substituents, which is very rare for complexes. (Formula Presented.) (Figure Presented.)",

keywords = "complexes with nitrogen ligands, mercury compounds, networks, triazines",

author = "Batten, {Stuart R.} and Hoskins, {Bernard F.} and Richard Robson",

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T1 - 2,4,6‐Tri(4‐pyridyl)‐1,3,5‐triazine as a 3‐Connecting Building Block for Infinite Nets

AU - Batten, Stuart R.

AU - Hoskins, Bernard F.

AU - Robson, Richard

PY - 1995/4/13

Y1 - 1995/4/13

N2 - A new three‐dimensional coordination network with cubic symmetry is displayed by the structure of 1 (shown on the right). Compound 1 is obtained from tri(4‐pyridyl)triazine ligands (tpt) and Hg2+ ions, and has a system of interconnected spacious cavities which are occupied by large numbers of solvent molecules and counterions. The coordination sphere of the Hg center is formed by six pyridine substituents, which is very rare for complexes. (Formula Presented.) (Figure Presented.)

AB - A new three‐dimensional coordination network with cubic symmetry is displayed by the structure of 1 (shown on the right). Compound 1 is obtained from tri(4‐pyridyl)triazine ligands (tpt) and Hg2+ ions, and has a system of interconnected spacious cavities which are occupied by large numbers of solvent molecules and counterions. The coordination sphere of the Hg center is formed by six pyridine substituents, which is very rare for complexes. (Formula Presented.) (Figure Presented.)

KW - complexes with nitrogen ligands

KW - mercury compounds

KW - networks

KW - triazines

UR - http://www.scopus.com/inward/record.url?scp=33745147891&partnerID=8YFLogxK

U2 - 10.1002/anie.199508201

DO - 10.1002/anie.199508201

M3 - Article

AN - SCOPUS:33745147891

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JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

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