2,2,7-Trichloro-3,4-dihydronaphthalen-1(2H)-one

Benvenuto Capuano; Ian Travers Crosby; Craig Macdonald Forsyth; James Kisup Shin

2,2,7-Trichloro-3,4-dihydronaphthalen-1(2H)-one

Benvenuto Capuano, Ian Travers Crosby, Craig Macdonald Forsyth, James Kisup Shin

Research output: Contribution to journal › Article › Research › peer-review

Abstract

The title compound, C10H7Cl3O, obtained as a major byproduct from a classical Schmidt reaction. The cyclohexyl ring is distorted from a classical chair conformation, as observed for monocyclic analogues, presumably due to conjugation of the planar annulated benzo ring and the ketone group (r.m.s. deviation 0.024 angstrom). There are no significant intermolecular interactions.

Original language	English
Pages (from-to)	02254 - 02254
Number of pages	1
Journal	Acta Crystallographica Section E: Structure Reports Online
Volume	65
Issue number	Part 9
Publication status	Published - 2009

Cite this

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title = "2,2,7-Trichloro-3,4-dihydronaphthalen-1(2H)-one",

abstract = "The title compound, C10H7Cl3O, obtained as a major byproduct from a classical Schmidt reaction. The cyclohexyl ring is distorted from a classical chair conformation, as observed for monocyclic analogues, presumably due to conjugation of the planar annulated benzo ring and the ketone group (r.m.s. deviation 0.024 angstrom). There are no significant intermolecular interactions.",

author = "Benvenuto Capuano and Crosby, {Ian Travers} and Forsyth, {Craig Macdonald} and Shin, {James Kisup}",

year = "2009",

language = "English",

volume = "65",

pages = "02254 -- 02254",

journal = "Acta Crystallographica Section E: Structure Reports Online",

issn = "1600-5368",

publisher = "International Union of Crystallography (IUCr)",

number = "Part 9",

}

TY - JOUR

T1 - 2,2,7-Trichloro-3,4-dihydronaphthalen-1(2H)-one

AU - Capuano, Benvenuto

AU - Crosby, Ian Travers

AU - Forsyth, Craig Macdonald

AU - Shin, James Kisup

PY - 2009

Y1 - 2009

N2 - The title compound, C10H7Cl3O, obtained as a major byproduct from a classical Schmidt reaction. The cyclohexyl ring is distorted from a classical chair conformation, as observed for monocyclic analogues, presumably due to conjugation of the planar annulated benzo ring and the ketone group (r.m.s. deviation 0.024 angstrom). There are no significant intermolecular interactions.

AB - The title compound, C10H7Cl3O, obtained as a major byproduct from a classical Schmidt reaction. The cyclohexyl ring is distorted from a classical chair conformation, as observed for monocyclic analogues, presumably due to conjugation of the planar annulated benzo ring and the ketone group (r.m.s. deviation 0.024 angstrom). There are no significant intermolecular interactions.

UR - http://scripts.iucr.org.ezproxy.lib.monash.edu.au/cgi-bin/paper?S1600536809032772

M3 - Article

SN - 1600-5368

VL - 65

SP - 2254

EP - 2254

JO - Acta Crystallographica Section E: Structure Reports Online

JF - Acta Crystallographica Section E: Structure Reports Online

IS - Part 9

ER -

2,2,7-Trichloro-3,4-dihydronaphthalen-1(2H)-one

Abstract

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