2,2'-Dipyridylamino-based ligands with substituted alkyl chain groups and their mononuclear-M(II) spin crossover complexes

Hayley Scott, Boujemaa Moubaraki, Nicolas Paradis, Guillaume Chastanet, Jean-Francois Letard, Stuart Robert Batten, Keith Spencer Murray

Research output: Contribution to journalArticleResearchpeer-review

8 Citations (Scopus)

Abstract

Four new alkyl chain appended dipyridylamino-substituted-s-triazine ligands have been incorporated into seven new, mononuclear MII compounds of type [MII(NCX)2(L)2] (where NCX = NCS- or NCSe-, L = dipyridylamino-substituted-s-triazine-based ligand and MII = Fe or Co). These complexes have been structurally and magnetically characterised. The magnetic consequence of varying the alkyl chain length has been investigated in terms of intermolecular interactions and crystallographic packing arrangements. For selected complexes photomagnetic LIESST (Light-Induced Excited Spin State Trapping) measurements have been performed revealing reversible photo-induced spin-state switching.
Original languageEnglish
Pages (from-to)7845-7857
Number of pages13
JournalJournal of Materials Chemistry C
Volume3
Issue number30
DOIs
Publication statusPublished - 2015

Cite this

Scott, Hayley ; Moubaraki, Boujemaa ; Paradis, Nicolas ; Chastanet, Guillaume ; Letard, Jean-Francois ; Batten, Stuart Robert ; Murray, Keith Spencer. / 2,2'-Dipyridylamino-based ligands with substituted alkyl chain groups and their mononuclear-M(II) spin crossover complexes. In: Journal of Materials Chemistry C. 2015 ; Vol. 3, No. 30. pp. 7845-7857.
@article{95592a8359c94750b7b79d9e07aadf4f,
title = "2,2'-Dipyridylamino-based ligands with substituted alkyl chain groups and their mononuclear-M(II) spin crossover complexes",
abstract = "Four new alkyl chain appended dipyridylamino-substituted-s-triazine ligands have been incorporated into seven new, mononuclear MII compounds of type [MII(NCX)2(L)2] (where NCX = NCS- or NCSe-, L = dipyridylamino-substituted-s-triazine-based ligand and MII = Fe or Co). These complexes have been structurally and magnetically characterised. The magnetic consequence of varying the alkyl chain length has been investigated in terms of intermolecular interactions and crystallographic packing arrangements. For selected complexes photomagnetic LIESST (Light-Induced Excited Spin State Trapping) measurements have been performed revealing reversible photo-induced spin-state switching.",
author = "Hayley Scott and Boujemaa Moubaraki and Nicolas Paradis and Guillaume Chastanet and Jean-Francois Letard and Batten, {Stuart Robert} and Murray, {Keith Spencer}",
year = "2015",
doi = "10.1039/c5tc00491h",
language = "English",
volume = "3",
pages = "7845--7857",
journal = "Journal of Materials Chemistry C",
issn = "2050-7526",
publisher = "The Royal Society of Chemistry",
number = "30",

}

2,2'-Dipyridylamino-based ligands with substituted alkyl chain groups and their mononuclear-M(II) spin crossover complexes. / Scott, Hayley; Moubaraki, Boujemaa; Paradis, Nicolas; Chastanet, Guillaume; Letard, Jean-Francois; Batten, Stuart Robert; Murray, Keith Spencer.

In: Journal of Materials Chemistry C, Vol. 3, No. 30, 2015, p. 7845-7857.

Research output: Contribution to journalArticleResearchpeer-review

TY - JOUR

T1 - 2,2'-Dipyridylamino-based ligands with substituted alkyl chain groups and their mononuclear-M(II) spin crossover complexes

AU - Scott, Hayley

AU - Moubaraki, Boujemaa

AU - Paradis, Nicolas

AU - Chastanet, Guillaume

AU - Letard, Jean-Francois

AU - Batten, Stuart Robert

AU - Murray, Keith Spencer

PY - 2015

Y1 - 2015

N2 - Four new alkyl chain appended dipyridylamino-substituted-s-triazine ligands have been incorporated into seven new, mononuclear MII compounds of type [MII(NCX)2(L)2] (where NCX = NCS- or NCSe-, L = dipyridylamino-substituted-s-triazine-based ligand and MII = Fe or Co). These complexes have been structurally and magnetically characterised. The magnetic consequence of varying the alkyl chain length has been investigated in terms of intermolecular interactions and crystallographic packing arrangements. For selected complexes photomagnetic LIESST (Light-Induced Excited Spin State Trapping) measurements have been performed revealing reversible photo-induced spin-state switching.

AB - Four new alkyl chain appended dipyridylamino-substituted-s-triazine ligands have been incorporated into seven new, mononuclear MII compounds of type [MII(NCX)2(L)2] (where NCX = NCS- or NCSe-, L = dipyridylamino-substituted-s-triazine-based ligand and MII = Fe or Co). These complexes have been structurally and magnetically characterised. The magnetic consequence of varying the alkyl chain length has been investigated in terms of intermolecular interactions and crystallographic packing arrangements. For selected complexes photomagnetic LIESST (Light-Induced Excited Spin State Trapping) measurements have been performed revealing reversible photo-induced spin-state switching.

UR - http://pubs.rsc.org/en/content/articlepdf/2015/tc/c5tc00491h

U2 - 10.1039/c5tc00491h

DO - 10.1039/c5tc00491h

M3 - Article

VL - 3

SP - 7845

EP - 7857

JO - Journal of Materials Chemistry C

JF - Journal of Materials Chemistry C

SN - 2050-7526

IS - 30

ER -