2-tert-Butoxy-1-phenyl-1-(2,2,6,6-tetramethylpiperidin-1-yloxy)ethane

Andrei S. Batsanov; Alistair J. Reid; Neil Cameron

doi:10.1107/S1600536805004976

2-tert-Butoxy-1-phenyl-1-(2,2,6,6-tetramethylpiperidin-1-yloxy)ethane

Andrei S. Batsanov
, Alistair J. Reid
, Neil Cameron

Research output: Contribution to journal › Article › Research › peer-review

Abstract

The molecular structure of C₂₁H₃₅NO₂ was analyzed. A solution of 2,2,6,6-tetramethylpiperidinyloxy and di-tert-butylperoxalate in styrene was prepared. It was found that the piperidine ring adopted a chair conformation with the N-O1 bond in an equatorial orientation. It was observed that the N-)1 distance was typical for a signle bond, while the N atom had pyramidal geometry, corresponding to sp ³.

Original language	English
Journal	Acta Crystallographica Section E: Structure Reports Online
Volume	61
Issue number	3
DOIs	https://doi.org/10.1107/S1600536805004976
Publication status	Published - 1 Mar 2005
Externally published	Yes

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title = "2-tert-Butoxy-1-phenyl-1-(2,2,6,6-tetramethylpiperidin-1-yloxy)ethane",

abstract = "The molecular structure of C21H35NO2 was analyzed. A solution of 2,2,6,6-tetramethylpiperidinyloxy and di-tert-butylperoxalate in styrene was prepared. It was found that the piperidine ring adopted a chair conformation with the N-O1 bond in an equatorial orientation. It was observed that the N-)1 distance was typical for a signle bond, while the N atom had pyramidal geometry, corresponding to sp 3.",

author = "Batsanov, \{Andrei S.\} and Reid, \{Alistair J.\} and Neil Cameron",

year = "2005",

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doi = "10.1107/S1600536805004976",

language = "English",

volume = "61",

journal = "Acta Crystallographica Section E: Structure Reports Online",

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publisher = "International Union of Crystallography (IUCr)",

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T1 - 2-tert-Butoxy-1-phenyl-1-(2,2,6,6-tetramethylpiperidin-1-yloxy)ethane

AU - Batsanov, Andrei S.

AU - Reid, Alistair J.

AU - Cameron, Neil

PY - 2005/3/1

Y1 - 2005/3/1

N2 - The molecular structure of C21H35NO2 was analyzed. A solution of 2,2,6,6-tetramethylpiperidinyloxy and di-tert-butylperoxalate in styrene was prepared. It was found that the piperidine ring adopted a chair conformation with the N-O1 bond in an equatorial orientation. It was observed that the N-)1 distance was typical for a signle bond, while the N atom had pyramidal geometry, corresponding to sp 3.

AB - The molecular structure of C21H35NO2 was analyzed. A solution of 2,2,6,6-tetramethylpiperidinyloxy and di-tert-butylperoxalate in styrene was prepared. It was found that the piperidine ring adopted a chair conformation with the N-O1 bond in an equatorial orientation. It was observed that the N-)1 distance was typical for a signle bond, while the N atom had pyramidal geometry, corresponding to sp 3.

UR - https://www.scopus.com/pages/publications/18544390031

U2 - 10.1107/S1600536805004976

DO - 10.1107/S1600536805004976

M3 - Article

AN - SCOPUS:18544390031

SN - 1600-5368

VL - 61

JO - Acta Crystallographica Section E: Structure Reports Online

JF - Acta Crystallographica Section E: Structure Reports Online

IS - 3

ER -

2-tert-Butoxy-1-phenyl-1-(2,2,6,6-tetramethylpiperidin-1-yloxy)ethane

Abstract

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