2-(10′,10′-Dimethyl-3′-sulfanylidene-4′- azatricyclo[5.2.1.01,5]decan-2′-yl)-10,10-dimethyl-4- azatricyclo[5.2.1.01,5]decane-3-thione

Ashley Walker, Craig M. Forsyth, Patrick Perlmutter

Research output: Contribution to journalArticleOtherpeer-review

Abstract

The title compound, C28H40N2O2S2, was obtained as a minor product from an anti-aldol reaction between the corresponding N-propionylthiolactam and benzaldehyde. The asymmetric unit contains one half-molecule, which is completed by inversion symmetry. The molecule displays a nearly eclipsed conformation along the central C - C bond with a C - C - C - C - torsion angle of 20.4 (3)°.

Original languageEnglish
JournalActa Crystallographica Section E: Structure Reports Online
Volume69
Issue number8
DOIs
Publication statusPublished - Aug 2013

Keywords

  • data-to-parameter ratio = 24.8
  • meanω(C - C) = 0.004 A °
  • Rfactor = 0.049
  • single-crystal X-ray study
  • T = 123 K
  • wRfactor = 0.100

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