1D Nanoconfined ordered-assembly reaction

Shijie Liu, Xiqi Zhang, Lei Jiang

Research output: Contribution to journalReview ArticleResearchpeer-review

18 Citations (Scopus)

Abstract

1D nanoconfined chemical reactions generally exhibit enhanced performance, as a consequence of nanoconfinement, yet the inherent mechanism of this nanoconfinement-enhanced performance remains elusive. Here, the authors' perspectives on 1D nanoconfined chemical reactions are first provided, followed by the 1D nanoconfined preassembled reactions. Then, ultrafast mass transport behaviors in biological and artificial nanochannels are discussed and the quantum-confined superfluid concept is introduced. Inspired by the programmed-assembly reaction in living organisms, a new concept of ordered-assembly reaction is proposed through combining quantum-confined superfluid with frontier molecular orbital theory, to understand the inherent mechanism of high-performance 1D nanoconfined chemical reactions. Finally, the prospective for future development of the ordered-assembly reaction concept is presented.

Original languageEnglish
Article number1900104
Number of pages9
JournalAdvanced Materials Interfaces
Volume6
Issue number8
DOIs
Publication statusPublished - 23 Apr 2019
Externally publishedYes

Keywords

  • frontier molecular orbital theory
  • nanochannels
  • nanoconfinement
  • ordered-assembly reaction
  • quantum-confined superfluid

Cite this