1,2-additions of phenylselenenyl halides to phosphaalkynes

Matthew D. Francis; Cameron Jones; Peter C. Junk; John L. Roberts

doi:10.1080/10426509708033693

1,2-additions of phenylselenenyl halides to phosphaalkynes

Matthew D. Francis, Cameron Jones, Peter C. Junk, John L. Roberts

Research output: Contribution to journal › Article › Research › peer-review

5 Citations (Scopus)

Abstract

The preparation of a variety of selenophosphaalkenes by addition of phenylseleneyl halides to phosphaalkynes is described. The process is stereoselective and largely regioselective. The stereoselectivity is explained by postulating the presence of a cyclic selenophosphirenylium cation. The reaction of one of the prepared selenophosphaalkenes with 'BuLi is discussed.

Original language	English
Pages (from-to)	23-34
Number of pages	12
Journal	Phosphorus, Sulfur and Silicon and the Related Elements
Volume	130
DOIs	https://doi.org/10.1080/10426509708033693
Publication status	Published - 1 Jan 1997
Externally published	Yes

Keywords

Crystal structure
Phenylselenenyl halide
Phosphaalkyne
Selenophosphaalkene
Selenophosphirenylium cation

Access to Document

10.1080/10426509708033693

Cite this

@article{fa20f640e98245e0a38a7f58549a81a9,

title = "1,2-additions of phenylselenenyl halides to phosphaalkynes",

abstract = "The preparation of a variety of selenophosphaalkenes by addition of phenylseleneyl halides to phosphaalkynes is described. The process is stereoselective and largely regioselective. The stereoselectivity is explained by postulating the presence of a cyclic selenophosphirenylium cation. The reaction of one of the prepared selenophosphaalkenes with 'BuLi is discussed.",

keywords = "Crystal structure, Phenylselenenyl halide, Phosphaalkyne, Selenophosphaalkene, Selenophosphirenylium cation",

author = "Francis, \{Matthew D.\} and Cameron Jones and Junk, \{Peter C.\} and Roberts, \{John L.\}",

year = "1997",

month = jan,

day = "1",

doi = "10.1080/10426509708033693",

language = "English",

volume = "130",

pages = "23--34",

journal = "Phosphorus, Sulfur and Silicon and the Related Elements",

issn = "1042-6507",

publisher = "Taylor \& Francis",

}

TY - JOUR

T1 - 1,2-additions of phenylselenenyl halides to phosphaalkynes

AU - Francis, Matthew D.

AU - Jones, Cameron

AU - Junk, Peter C.

AU - Roberts, John L.

PY - 1997/1/1

Y1 - 1997/1/1

N2 - The preparation of a variety of selenophosphaalkenes by addition of phenylseleneyl halides to phosphaalkynes is described. The process is stereoselective and largely regioselective. The stereoselectivity is explained by postulating the presence of a cyclic selenophosphirenylium cation. The reaction of one of the prepared selenophosphaalkenes with 'BuLi is discussed.

AB - The preparation of a variety of selenophosphaalkenes by addition of phenylseleneyl halides to phosphaalkynes is described. The process is stereoselective and largely regioselective. The stereoselectivity is explained by postulating the presence of a cyclic selenophosphirenylium cation. The reaction of one of the prepared selenophosphaalkenes with 'BuLi is discussed.

KW - Crystal structure

KW - Phenylselenenyl halide

KW - Phosphaalkyne

KW - Selenophosphaalkene

KW - Selenophosphirenylium cation

UR - http://www.scopus.com/inward/record.url?scp=0031324150&partnerID=8YFLogxK

U2 - 10.1080/10426509708033693

DO - 10.1080/10426509708033693

M3 - Article

AN - SCOPUS:0031324150

SN - 1042-6507

VL - 130

SP - 23

EP - 34

JO - Phosphorus, Sulfur and Silicon and the Related Elements

JF - Phosphorus, Sulfur and Silicon and the Related Elements

ER -

1,2-additions of phenylselenenyl halides to phosphaalkynes

Abstract

Keywords

Access to Document

Other files and links

Cite this