TY - JOUR
T1 - 1′-Methyl-4′-[4-(trifluoromethyl)phenyl]dispiro[acenaphthylene- 1,2′-pyrrolidine-3′,2′′-indane]-2,1′′(1H) -dione
AU - Wei, Ang Chee
AU - Ali, Mohamed Ashraf
AU - Choon, Tan Soo
AU - Arshad, Suhana
AU - Razak, Ibrahim Abdul
N1 - Copyright:
Copyright 2012 Elsevier B.V., All rights reserved.
PY - 2012/5
Y1 - 2012/5
N2 - In the title compound, C31H22F3NO 2, the pyrrolidine and cyclo-pentane rings within the dihydro-indene ring system are in envelope conformations, with the N atom and the spiro-C atom at the flap, respectively. An intra-molecular C - H⋯O hydrogen bond forms an S(8) ring motif. The mean plane through the pyrrolidine ring [r.m.s. deviation = 0.179 (2) Å] makes dihedral angles of 86.30 (13), 88.99 (10) and 79.69 (11)°with the benzene ring, the dihydro-acenaphthyl-ene ring and the mean plane of the indane system, respectively. In the crystal, molecules are linked by C - H⋯O and C - H⋯N hydrogen bonds into a two-dimensional network parallel to the ac plane. C - H⋯π inter-actions further stabilize the crystal structure.
AB - In the title compound, C31H22F3NO 2, the pyrrolidine and cyclo-pentane rings within the dihydro-indene ring system are in envelope conformations, with the N atom and the spiro-C atom at the flap, respectively. An intra-molecular C - H⋯O hydrogen bond forms an S(8) ring motif. The mean plane through the pyrrolidine ring [r.m.s. deviation = 0.179 (2) Å] makes dihedral angles of 86.30 (13), 88.99 (10) and 79.69 (11)°with the benzene ring, the dihydro-acenaphthyl-ene ring and the mean plane of the indane system, respectively. In the crystal, molecules are linked by C - H⋯O and C - H⋯N hydrogen bonds into a two-dimensional network parallel to the ac plane. C - H⋯π inter-actions further stabilize the crystal structure.
UR - http://www.scopus.com/inward/record.url?scp=84860705951&partnerID=8YFLogxK
U2 - 10.1107/S1600536812013645
DO - 10.1107/S1600536812013645
M3 - Article
AN - SCOPUS:84860705951
SN - 2056-9890
VL - 68
SP - o1296-o1297
JO - Acta Crystallographica Section E: Structure Reports Online
JF - Acta Crystallographica Section E: Structure Reports Online
IS - 5
ER -