新型三维微孔砷酸铟InAsO4(H2O)2的合成及结构

Zhen Xia Chen; Lin Hong Weng; Ya Ming Zhou; Hao Yu Zhang; Dong Yuan Zhao

新型三维微孔砷酸铟InAsO4(H2O)2的合成及结构

Translated title of the contribution: Synthesis and structure of a new three-dimensional microporous indium arsenate

Zhen Xia Chen, Lin Hong Weng, Ya Ming Zhou, Hao Yu Zhang, Dong Yuan Zhao

Research output: Contribution to journal › Article › Research › peer-review

3 Citations (Scopus)

Abstract

A new three-dimensional microporous indium arsenate has been synthesized for the first time from the hydrothermal reaction of H₂O, InCl ₃·4H₂O, H₃AsO₄ and C ₆H₁₂N₂·6H₂O. Single crystal X-ray diffraction studies show that it has an orthorhombic (symmetry space group Pbca), with a = 0.9090(4) nm, b = 1.0344 (4) nm, c = 1.0468(4) nm. It's asymmetry unit is InAsO₄(H₂O)₂, which produces a 4-ring and 6-ring 1D channel along the a and b axis, respectively. It also contains a cage-like structure surrounded by 4,6,8-rings. The organic amine is not occluded in the structure. This structure is the first indium arsenate analog of InPO₄-1.

Translated title of the contribution	Synthesis and structure of a new three-dimensional microporous indium arsenate
Original language	Chinese
Pages (from-to)	305-309
Number of pages	5
Journal	Acta Chimica Sinica
Volume	60
Issue number	2
Publication status	Published - 1 May 2002
Externally published	Yes

Keywords

Characterization
Hydrothermal synthesis
Indium arsenate
Microporous material
Structure

Cite this

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title = "新型三维微孔砷酸铟InAsO4(H2O)2的合成及结构",

abstract = "A new three-dimensional microporous indium arsenate has been synthesized for the first time from the hydrothermal reaction of H2O, InCl 3·4H2O, H3AsO4 and C 6H12N2·6H2O. Single crystal X-ray diffraction studies show that it has an orthorhombic (symmetry space group Pbca), with a = 0.9090(4) nm, b = 1.0344 (4) nm, c = 1.0468(4) nm. It's asymmetry unit is InAsO4(H2O)2, which produces a 4-ring and 6-ring 1D channel along the a and b axis, respectively. It also contains a cage-like structure surrounded by 4,6,8-rings. The organic amine is not occluded in the structure. This structure is the first indium arsenate analog of InPO4-1.",

keywords = "Characterization, Hydrothermal synthesis, Indium arsenate, Microporous material, Structure",

author = "Chen, {Zhen Xia} and Weng, {Lin Hong} and Zhou, {Ya Ming} and Zhang, {Hao Yu} and Zhao, {Dong Yuan}",

year = "2002",

month = may,

day = "1",

language = "Chinese",

volume = "60",

pages = "305--309",

journal = "Acta Chimica Sinica",

issn = "0567-7351",

publisher = "Shanghai Institute of Organic Chemistry",

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TY - JOUR

T1 - 新型三维微孔砷酸铟InAsO4(H2O)2的合成及结构

AU - Chen, Zhen Xia

AU - Weng, Lin Hong

AU - Zhou, Ya Ming

AU - Zhang, Hao Yu

AU - Zhao, Dong Yuan

PY - 2002/5/1

Y1 - 2002/5/1

N2 - A new three-dimensional microporous indium arsenate has been synthesized for the first time from the hydrothermal reaction of H2O, InCl 3·4H2O, H3AsO4 and C 6H12N2·6H2O. Single crystal X-ray diffraction studies show that it has an orthorhombic (symmetry space group Pbca), with a = 0.9090(4) nm, b = 1.0344 (4) nm, c = 1.0468(4) nm. It's asymmetry unit is InAsO4(H2O)2, which produces a 4-ring and 6-ring 1D channel along the a and b axis, respectively. It also contains a cage-like structure surrounded by 4,6,8-rings. The organic amine is not occluded in the structure. This structure is the first indium arsenate analog of InPO4-1.

AB - A new three-dimensional microporous indium arsenate has been synthesized for the first time from the hydrothermal reaction of H2O, InCl 3·4H2O, H3AsO4 and C 6H12N2·6H2O. Single crystal X-ray diffraction studies show that it has an orthorhombic (symmetry space group Pbca), with a = 0.9090(4) nm, b = 1.0344 (4) nm, c = 1.0468(4) nm. It's asymmetry unit is InAsO4(H2O)2, which produces a 4-ring and 6-ring 1D channel along the a and b axis, respectively. It also contains a cage-like structure surrounded by 4,6,8-rings. The organic amine is not occluded in the structure. This structure is the first indium arsenate analog of InPO4-1.

KW - Characterization

KW - Hydrothermal synthesis

KW - Indium arsenate

KW - Microporous material

KW - Structure

UR - http://www.scopus.com/inward/record.url?scp=0042369151&partnerID=8YFLogxK

M3 - Article

AN - SCOPUS:0042369151

SN - 0567-7351

VL - 60

SP - 305

EP - 309

JO - Acta Chimica Sinica

JF - Acta Chimica Sinica

IS - 2

ER -

新型三维微孔砷酸铟InAsO4(H2O)2的合成及结构

Abstract

Keywords

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