π-Bonding versus oligomerisation in the aromatic anions [C 6H4N2E]-: Formation of the cyclic tetrameric tetraanion [C6H4N2Sb] 44-

Felipe García; Robert J. Less; Vesal Naseri; Mary McPartlin; Jeremy M. Rawson; Dominic S. Wright

doi:10.1039/b718512j

π-Bonding versus oligomerisation in the aromatic anions [C ₆H₄N₂E]^-: Formation of the cyclic tetrameric tetraanion [C₆H₄N₂Sb] ₄^4-

Felipe García
, Robert J. Less
, Vesal Naseri
, Mary McPartlin
, Jeremy M. Rawson
, Dominic S. Wright

Research output: Contribution to journal › Article › Research › peer-review

6 Citations (Scopus)

Abstract

The reaction of 1,2-(NH₂)₂C₆H₄ with Sb(NMe₂)₃/ⁿBuLi gives the formally-aromatic heterocyclic anion [C₆H₄N ₂Sb]^- which oligomerises into a cyclic tetrameric arrangement in the complex [C₆H₄N₂SbLi• PMDETA]₄ (1) (PMDETA = {Me₂NCH₂CH ₂}₂NMe) using a donor-acceptor bonding mode that is unique in related main group heterocyclic anions.

Original language	English
Pages (from-to)	997-999
Number of pages	3
Journal	Dalton Transactions
Issue number	8
DOIs	https://doi.org/10.1039/b718512j
Publication status	Published - 2008
Externally published	Yes

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10.1039/b718512j

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title = "π-Bonding versus oligomerisation in the aromatic anions [C 6H4N2E]-: Formation of the cyclic tetrameric tetraanion [C6H4N2Sb] 44-",

abstract = "The reaction of 1,2-(NH2)2C6H4 with Sb(NMe2)3/nBuLi gives the formally-aromatic heterocyclic anion [C6H4N 2Sb]- which oligomerises into a cyclic tetrameric arrangement in the complex [C6H4N2SbLi• PMDETA]4 (1) (PMDETA = \{Me2NCH2CH 2\}2NMe) using a donor-acceptor bonding mode that is unique in related main group heterocyclic anions.",

author = "Felipe Garc{\'i}a and Less, \{Robert J.\} and Vesal Naseri and Mary McPartlin and Rawson, \{Jeremy M.\} and Wright, \{Dominic S.\}",

year = "2008",

doi = "10.1039/b718512j",

language = "English",

pages = "997--999",

journal = "Dalton Transactions",

issn = "1477-9226",

publisher = "The Royal Society of Chemistry",

number = "8",

}

TY - JOUR

T1 - π-Bonding versus oligomerisation in the aromatic anions [C 6H4N2E]-

T2 - Formation of the cyclic tetrameric tetraanion [C6H4N2Sb] 44-

AU - García, Felipe

AU - Less, Robert J.

AU - Naseri, Vesal

AU - McPartlin, Mary

AU - Rawson, Jeremy M.

AU - Wright, Dominic S.

PY - 2008

Y1 - 2008

N2 - The reaction of 1,2-(NH2)2C6H4 with Sb(NMe2)3/nBuLi gives the formally-aromatic heterocyclic anion [C6H4N 2Sb]- which oligomerises into a cyclic tetrameric arrangement in the complex [C6H4N2SbLi• PMDETA]4 (1) (PMDETA = {Me2NCH2CH 2}2NMe) using a donor-acceptor bonding mode that is unique in related main group heterocyclic anions.

AB - The reaction of 1,2-(NH2)2C6H4 with Sb(NMe2)3/nBuLi gives the formally-aromatic heterocyclic anion [C6H4N 2Sb]- which oligomerises into a cyclic tetrameric arrangement in the complex [C6H4N2SbLi• PMDETA]4 (1) (PMDETA = {Me2NCH2CH 2}2NMe) using a donor-acceptor bonding mode that is unique in related main group heterocyclic anions.

UR - https://www.scopus.com/pages/publications/39349110224

U2 - 10.1039/b718512j

DO - 10.1039/b718512j

M3 - Article

AN - SCOPUS:39349110224

SN - 1477-9226

SP - 997

EP - 999

JO - Dalton Transactions

JF - Dalton Transactions

IS - 8

ER -

π-Bonding versus oligomerisation in the aromatic anions [C 6H4N2E]-: Formation of the cyclic tetrameric tetraanion [C6H4N2Sb] 44-

Abstract

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π-Bonding versus oligomerisation in the aromatic anions [C ₆H₄N₂E]^-: Formation of the cyclic tetrameric tetraanion [C₆H₄N₂Sb] ₄^4-