μ-acetato-μ-aqua-μ-hydroxo-bis[(1,4-dimethyl-1,4,7- triazacyclononane-κ3N)-copper(II)] diperchlorate

David J. Elliot; Lisandra L. Martin; Max R. Taylor

doi:10.1107/S0108270198004375

μ-acetato-μ-aqua-μ-hydroxo-bis[(1,4-dimethyl-1,4,7- triazacyclononane-κ³N)-copper(II)] diperchlorate

David J. Elliot
, Lisandra L. Martin
, Max R. Taylor

Research output: Contribution to journal › Article › Research › peer-review

13 Citations (Scopus)

Abstract

The structural characterization of the title complex, [Cu₂(OH)(C₂H₃O₂)(C₈H ₁₉N₃)₂(H₂O)](CIO₄) ₂, provides only the third example of a binuclear copper complex containing a bridging water molecule. The three bridging groups (aqua, acetato and hydroxo) are all different, a rare feature for spontaneous self-assembly reactions. The resulting geometry about the two Cu atoms is distorted octahedral, with the Cu - O(H) distance of 1.963 (2) Å distinguished from the Cu - Q(H₂) distance of 2.737 (5) Å, The cation has crystallographically imposed mirror symmetry.

Original language	English
Pages (from-to)	1259-1261
Number of pages	3
Journal	Acta Crystallographica Section C: Crystal Structure Communications
Volume	54
Issue number	9
DOIs	https://doi.org/10.1107/S0108270198004375
Publication status	Published - 15 Sept 1998
Externally published	Yes

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title = "μ-acetato-μ-aqua-μ-hydroxo-bis[(1,4-dimethyl-1,4,7- triazacyclononane-κ3N)-copper(II)] diperchlorate",

abstract = "The structural characterization of the title complex, [Cu2(OH)(C2H3O2)(C8H 19N3)2(H2O)](CIO4) 2, provides only the third example of a binuclear copper complex containing a bridging water molecule. The three bridging groups (aqua, acetato and hydroxo) are all different, a rare feature for spontaneous self-assembly reactions. The resulting geometry about the two Cu atoms is distorted octahedral, with the Cu - O(H) distance of 1.963 (2) {\AA} distinguished from the Cu - Q(H2) distance of 2.737 (5) {\AA}, The cation has crystallographically imposed mirror symmetry.",

author = "Elliot, \{David J.\} and Martin, \{Lisandra L.\} and Taylor, \{Max R.\}",

year = "1998",

month = sep,

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doi = "10.1107/S0108270198004375",

language = "English",

volume = "54",

pages = "1259--1261",

journal = "Acta Crystallographica Section C: Crystal Structure Communications",

issn = "0108-2701",

publisher = "International Union of Crystallography (IUCr)",

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TY - JOUR

T1 - μ-acetato-μ-aqua-μ-hydroxo-bis[(1,4-dimethyl-1,4,7- triazacyclononane-κ3N)-copper(II)] diperchlorate

AU - Elliot, David J.

AU - Martin, Lisandra L.

AU - Taylor, Max R.

PY - 1998/9/15

Y1 - 1998/9/15

N2 - The structural characterization of the title complex, [Cu2(OH)(C2H3O2)(C8H 19N3)2(H2O)](CIO4) 2, provides only the third example of a binuclear copper complex containing a bridging water molecule. The three bridging groups (aqua, acetato and hydroxo) are all different, a rare feature for spontaneous self-assembly reactions. The resulting geometry about the two Cu atoms is distorted octahedral, with the Cu - O(H) distance of 1.963 (2) Å distinguished from the Cu - Q(H2) distance of 2.737 (5) Å, The cation has crystallographically imposed mirror symmetry.

AB - The structural characterization of the title complex, [Cu2(OH)(C2H3O2)(C8H 19N3)2(H2O)](CIO4) 2, provides only the third example of a binuclear copper complex containing a bridging water molecule. The three bridging groups (aqua, acetato and hydroxo) are all different, a rare feature for spontaneous self-assembly reactions. The resulting geometry about the two Cu atoms is distorted octahedral, with the Cu - O(H) distance of 1.963 (2) Å distinguished from the Cu - Q(H2) distance of 2.737 (5) Å, The cation has crystallographically imposed mirror symmetry.

UR - https://www.scopus.com/pages/publications/0010731854

U2 - 10.1107/S0108270198004375

DO - 10.1107/S0108270198004375

M3 - Article

AN - SCOPUS:0010731854

SN - 0108-2701

VL - 54

SP - 1259

EP - 1261

JO - Acta Crystallographica Section C: Crystal Structure Communications

JF - Acta Crystallographica Section C: Crystal Structure Communications

IS - 9

ER -

μ-acetato-μ-aqua-μ-hydroxo-bis[(1,4-dimethyl-1,4,7- triazacyclononane-κ3N)-copper(II)] diperchlorate

Abstract

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μ-acetato-μ-aqua-μ-hydroxo-bis[(1,4-dimethyl-1,4,7- triazacyclononane-κ³N)-copper(II)] diperchlorate