TY - JOUR
T1 - μ-acetato-μ-aqua-μ-hydroxo-bis[(1,4-dimethyl-1,4,7- triazacyclononane-κ3N)-copper(II)] diperchlorate
AU - Elliot, David J.
AU - Martin, Lisandra L.
AU - Taylor, Max R.
PY - 1998/9/15
Y1 - 1998/9/15
N2 - The structural characterization of the title complex, [Cu2(OH)(C2H3O2)(C8H 19N3)2(H2O)](CIO4) 2, provides only the third example of a binuclear copper complex containing a bridging water molecule. The three bridging groups (aqua, acetato and hydroxo) are all different, a rare feature for spontaneous self-assembly reactions. The resulting geometry about the two Cu atoms is distorted octahedral, with the Cu - O(H) distance of 1.963 (2) Å distinguished from the Cu - Q(H2) distance of 2.737 (5) Å, The cation has crystallographically imposed mirror symmetry.
AB - The structural characterization of the title complex, [Cu2(OH)(C2H3O2)(C8H 19N3)2(H2O)](CIO4) 2, provides only the third example of a binuclear copper complex containing a bridging water molecule. The three bridging groups (aqua, acetato and hydroxo) are all different, a rare feature for spontaneous self-assembly reactions. The resulting geometry about the two Cu atoms is distorted octahedral, with the Cu - O(H) distance of 1.963 (2) Å distinguished from the Cu - Q(H2) distance of 2.737 (5) Å, The cation has crystallographically imposed mirror symmetry.
UR - http://www.scopus.com/inward/record.url?scp=0010731854&partnerID=8YFLogxK
U2 - 10.1107/S0108270198004375
DO - 10.1107/S0108270198004375
M3 - Article
AN - SCOPUS:0010731854
VL - 54
SP - 1259
EP - 1261
JO - Acta Crystallographica Section C: Structural Chemistry
JF - Acta Crystallographica Section C: Structural Chemistry
SN - 2053-2296
IS - 9
ER -