[(η5-C5H5)Fe(CO)2] 2Ga3Cl3(OSiMe2OSiMe 2O)2: A diiron complex of a tetracyclic trigallasiloxane

Natalie R. Bunn, Simon Aldridge, Cameron Jones

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Abstract

The structure of the penta-metallic diiron trigallasiloxane, [η5-C5H5)Fe(CO)2] 2Ga3Cl3(OSiMe2 OSiMe 2O)2, reveals two distinct gallium coordination environments and Fe-Ga bond lengths (2.3258(6) Å), consistent with bonding of the iron centres to four-coordinate gallyl ligands.

Original languageEnglish
Pages (from-to)425-426
Number of pages2
JournalApplied Organometallic Chemistry
Volume18
Issue number8
DOIs
Publication statusPublished - 1 Aug 2004

Keywords

  • Crystal structure
  • Gallium
  • Gallyl
  • Iron
  • Siloxane

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