Project Details
Project Description
In this project, innovative approaches will be employed to access new, and fundamentally important, classes
of low oxidation state main group compounds, the electronic properties and reactivity of which will be readily
tuned to mimic those of noble transition metal complexes. For the first time, these attributes will be
harnessed to establish such compounds as cheap and sustainable alternatives to the expensive and toxic
transition metal catalysts that are currently essential to numerous synthetic processes utilised in academia
and industry. The involvement of a synergistic international network of collaborators will be central to the
success of this project, which offers major academic, environmental and economic benefits to Australia.
of low oxidation state main group compounds, the electronic properties and reactivity of which will be readily
tuned to mimic those of noble transition metal complexes. For the first time, these attributes will be
harnessed to establish such compounds as cheap and sustainable alternatives to the expensive and toxic
transition metal catalysts that are currently essential to numerous synthetic processes utilised in academia
and industry. The involvement of a synergistic international network of collaborators will be central to the
success of this project, which offers major academic, environmental and economic benefits to Australia.
| Status | Finished |
|---|---|
| Effective start/end date | 1/03/15 → 31/12/20 |
Funding
- ARC - Australian Research Council: A$613,400.00
- Monash University
- University of Oxford
Research output
- 6 Article
-
Extremely bulky secondary phosphinoamines as substituents for sterically hindered aminosilanes
Bottcher, T. & Jones, C., 2015, In: Dalton Transactions. 44, 33, p. 14842-14853 12 p.Research output: Contribution to journal › Article › Research › peer-review
13 Link opens in a new tab Citations (Scopus) -
Reaction mechanism of the symmetry-forbidden [2+2] addition of ethylene and acetylene to amido-substituted digermynes and distannynes Ph2N-EE-NPh2, (E=Ge, Sn): a theoretical study
Zhao, L., Jones, C. & Frenking, G., 2015, In: Chemistry - A European Journal. 21, 35, p. 12405-12413 9 p.Research output: Contribution to journal › Article › Research › peer-review
25 Link opens in a new tab Citations (Scopus) -
Reactivity of amido-digermynes, LGeGeL (L = bulky amide), toward olefins and related molecules: facile reduction, C-H activation, and reversible cycloaddition of unsaturated substrates
Hadlington, T. J., Li, J., Hermann, M., Davey, A., Frenking, G. & Jones, C., 2015, In: Organometallics. 34, 13, p. 3175-3185 11 p.Research output: Contribution to journal › Article › Research › peer-review
66 Link opens in a new tab Citations (Scopus)