Large Amplitude Fourier Transformed Voltammetry with Advanced Data Evaluation Strategies: A Roadmap for Tackling Stiff Problems in Electrochemistry

A roadmap based on information rich Large Amplitude Fourier Transformed AC Voltammetry has been developed to tackle identified stiff problems in dynamic electrochemistry at a state-of-the-art level. Advanced e-science tools will provide highly sophisticated methods of data analysis. Complete integration with homebuilt second generation instrumentation and universal simulation software will provide unprecedented levels of insight. Sensitivity differences in contributions from electron transfer, coupled chemistry, uncompensated resistance and capacitance can be exploited when very large data sets are sub-divided into an extensive series of higher harmonics and other components, all being derived from a single experiment.